Enhancement adsorption of hexavalent chromium from aqueous solution on polypyrrole using ethylamine group

被引:8
作者
Liu, Xiaoqin [1 ,2 ]
Liao, Yunwen [3 ]
Gao, Hejun [1 ,2 ]
机构
[1] China West Normal Univ, Inst Appl Chem, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong, Peoples R China
[2] China West Normal Univ, Inst Appl Chem, Nanchong, Peoples R China
[3] China West Normal Univ, Coll Environm Sci & Engn, Nanchong, Peoples R China
关键词
Adsorption; adsorption mechanism; chromium(VI); functionalized; pyrrole; CR(VI) REMOVAL; FACILE SYNTHESIS; RAPID REMOVAL; METAL-CATIONS; ADSORBENTS; COMPOSITE; PERFORMANCE; BLUE; NANOFIBERS; CELLULOSE;
D O I
10.1080/01932691.2017.1404917
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel nanospheres adsorbent was successfully prepared using functionalized 1H-Pyrrole-1-ethanamine by homopolymerization. It could be easily protonated to form double-charged repeating structural units on the surface of nanospheres. The physic-chemical properties were characterized by SEM, TGA, XPS and Zeta potential. The effects of initial pH, adsorbent dosage, contact time, initial concentration, and ionic strength were studied in detail. The maximum adsorption capacity of Chromium(VI) was about 729.09mgg(-1) at room temperature. Electrostatic attraction played an important role in the adsorption process and the size of the ion group had a greater effect on the adsorption performance than the charge. [GRAPHICS] .
引用
收藏
页码:1394 / 1402
页数:9
相关论文
共 52 条
[1]   Adsorption of chromium(VI) from aqueous solutions by glycidylmethacrylate-grafted-densified cellulose with quaternary ammonium groups [J].
Anirudhan, T. S. ;
Nima, J. ;
Divya, P. L. .
APPLIED SURFACE SCIENCE, 2013, 279 :441-449
[2]   Modification of mesoporous silica magnetite nanoparticles by 3-aminopropyltriethoxysilane for the removal of Cr(VI) from aqueous solution [J].
Araghi, Samira Hozhabr ;
Entezari, Mohammad H. ;
Chamsaz, Mahmoud .
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 218 :101-111
[3]   Surface functionalized nanofibers for the removal of chromium(VI) from aqueous solutions [J].
Avila, M. ;
Burks, T. ;
Akhtar, F. ;
Gothelid, M. ;
Lansaker, P. C. ;
Toprak, M. S. ;
Muhammed, M. ;
Uheida, A. .
CHEMICAL ENGINEERING JOURNAL, 2014, 245 :201-209
[4]   Removal of fluoride from aqueous solution by polypyrrole/Fe3O4 magnetic nanocomposite [J].
Bhaumik, Madhumita ;
Leswifi, Taile Yvonne ;
Maity, Arjun ;
Srinivasu, V. V. ;
Onyango, Maurice S. .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 186 (01) :150-159
[5]   Polypyrrole/Sulfonated Graphene Composite as Electrode Material for Supercapacitor [J].
Bora, Chandramika ;
Sharma, Jahnabi ;
Dolui, Swapan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (51) :29688-29694
[6]   Synthesis of Magnetic Gelatin and Its Adsorption Property for Cr(VI) [J].
Chen, Guangxin ;
Qiao, Congde ;
Wang, Yang ;
Yao, Jinshui .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (40) :15576-15581
[7]   Adsorbent synthesis of polypyrrole/TiO2 for effective fluoride removal from aqueous solution for drinking water purification: Adsorbent characterization and adsorption mechanism [J].
Chen, Jie ;
Shu, Chiajung ;
Wang, Ning ;
Feng, Jiangtao ;
Ma, Hongyu ;
Yan, Wei .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 495 :44-52
[8]   Influence of metal oxides on the adsorption characteristics of PPy/metal oxides for Methylene Blue [J].
Chen, Jie ;
Feng, Jiangtao ;
Yan, Wei .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 475 :26-35
[9]   Sepiolite Fiber Oriented-Polypyrrole Nanofibers for Efficient Chromium(VI) Removal from Aqueous Solution [J].
Chen, Jun ;
Hong, Xiaoqin ;
Xie, Qingdong ;
Li, Diankai ;
Zhang, Qianfeng .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (07) :2275-2282
[10]   Removal of mercury and methylene blue from aqueous solution by xanthate functionalized magnetic graphene oxide: Sorption kinetic and uptake mechanism [J].
Cui, Limei ;
Guo, Xiaoyao ;
Wei, Qin ;
Wang, Yaoguang ;
Gao, Liang ;
Yan, Liangguo ;
Yan, Tao ;
Du, Bin .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 439 :112-120