A Luminescent Molecular Thermometer for Long-Term Absolute Temperature Measurements at the Nanoscale

被引:419
作者
Brites, Carlos D. S. [3 ,4 ]
Lima, Patricia P. [3 ,4 ]
Silva, Nuno J. O. [3 ,4 ]
Millan, Angel [1 ,2 ]
Amaral, Vitor S. [3 ,4 ]
Palacio, Fernando [1 ,2 ]
Carlos, Luis D. [3 ,4 ]
机构
[1] Univ Zaragoza, CSIC, Dept Fis Mat Condensada, Fac Ciencias, E-50009 Zaragoza, Spain
[2] Univ Zaragoza, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[3] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal
[4] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal
关键词
ORGANIC-INORGANIC HYBRIDS; PHOSPHOR; FLUORESCENCE; NANOPARTICLES; EUROPIUM(III); SPECTROSCOPY; CONVERSION; LIFETIME; SENSORS;
D O I
10.1002/adma.201001780
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A unique Eu3+/Tb3+ luminescent self-referencing nanothermometer allowing absolute measurements in the 10-350 K temperature range and sub-micrometer spatial resolution is reported (see Figure). It has up to 4.9%K-1 temperature sensitivity and high photostability for long-term use. The combination of molecular thermometry, superparamagnetism and luminescence in a nanometric host matrix provides multifunctionality opening the way for new exciting applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4499 / 4504
页数:6
相关论文
共 37 条
  • [1] AC thermal imaging of a microwire with a fluorescent nanocrystal: Influence of the near field on the thermal contrast
    Aigouy, Lionel
    Saidi, Elika
    Lalouat, Loic
    Labeguerie-Egea, Jessica
    Mortier, Michel
    Loew, Peter
    Bergaud, Christian
    [J]. JOURNAL OF APPLIED PHYSICS, 2009, 106 (07)
  • [2] Fluorescence thermometer based on the photoluminescence intensity ratio in Tb doped phosphor materials
    Aizawa, H
    Katsumata, T
    Komuro, S
    Morikawa, T
    Ishizawa, H
    Toba, E
    [J]. SENSORS AND ACTUATORS A-PHYSICAL, 2006, 126 (01) : 78 - 82
  • [3] Nanoscale thermometry via the fluorescence of YAG:Ce phosphor particles:: measurements from 7 to 77 °C
    Allison, SW
    Gillies, GT
    Rondinone, AJ
    Cates, MR
    [J]. NANOTECHNOLOGY, 2003, 14 (08) : 859 - 863
  • [4] Remote thermometry with thermographic phosphors: Instrumentation and applications
    Allison, SW
    Gillies, GT
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (07) : 2615 - 2650
  • [5] Noncontact two-color luminescence thermometry based on intramolecular luminophore cyclization within an ionic liquid
    Baker, GA
    Baker, SN
    McCleskey, TM
    [J]. CHEMICAL COMMUNICATIONS, 2003, (23) : 2932 - 2933
  • [6] Bermudez VD, 1999, CHEM MATER, V11, P569
  • [7] Fine-tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII, and TmIII
    Carlos, LD
    Ferreira, RAS
    Rainho, JP
    Bermudez, VD
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (11-12) : 819 - 823
  • [8] Lanthanide-Containing Light-Emitting Organic-Inorganic Hybrids: A Bet on the Future
    Carlos, Luis D.
    Ferreira, Rute A. S.
    Bermudez, Veronica de Zea
    Ribeiro, Sidney J. L.
    [J]. ADVANCED MATERIALS, 2009, 21 (05) : 509 - 534
  • [9] A dual fluorescence temperature sensor based on perylene/exciplex interconversion
    Chandrasekharan, N
    Kelly, LA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (40) : 9898 - 9899
  • [10] Review of temperature measurement
    Childs, PRN
    Greenwood, JR
    Long, CA
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (08) : 2959 - 2978