Reversible addition-fragmentation chain transfer polymerization of styrene initiated by tetraethylthiuram disulfide

被引：9

作者：

Wang, XY ^{[1
]}

Zhu, J ^{[1
]}

Zhou, D ^{[1
]}

Zhu, XL ^{[1
]}

机构：

[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China

来源：

POLYMER | 2005年 / 46卷 / 10期

关键词：

reversible addition-fragmentation chain transfer (RAFT) polymerization; 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN); tetraethylthiuram disulfide (TETD);

D O I：

10.1016/j.polymer.2005.02.101

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The RAFT polymerization of styrene in bulk was carried out using tetraethylthiuram disulfide (TETD) as an initiator and 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as a chain transfer agent at different temperatures. The results of the polymerization showed that TETD could initiate the RAFT polymerization of styrene in the living way. The kinetics of the polymerization showed first order. The molecular weights of the polymers increased linearly with conversions and were close to the theoretical values (M-n,M-th). The polydispersities of the polymers remained relatively narrow (< 1.3). The structure of the polymer was characterized by H-1 NMR. The result showed that there were moieties of CPDN and TETD attained at the end of the polymer. Using these double functional end capped polymers, the chain-extension experiments were successfully carried out not only in the conventional RAFT polymerization way, but also under UV irradiation. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3515 / 3521

页数：7

共 31 条

[11] Reverse atom transfer radical polymerization of styrene in the presence of tetraethylthiuram disulfide [J].

Li, P ;

Qiu, KY .

POLYMER, 2002, 43 (10) :3019-3024

[12] Block and star block copolymers by mechanism transformation 9: Preparation and characterization of poly(methyl methacrylate)/poly(1,3-dioxepane)/polystyrene ABC miktoarm star copolymers by combination of reversible addition-fragmentation chain-transfer polymerization and cationic ring-opening polymerization [J].

Li, YG ;

Wang, YM ;

Pan, CY .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (09) :1243-1250

[13] Dihydroxyl-terminated telechelic polymers prepared by RAFT polymerization using functional trithiocarbonate as chain transfer agent [J].

Liu, J ;

Hong, CY ;

Pan, CY .

POLYMER, 2004, 45 (13) :4413-4421

[14] Synthesis and characterization of poly(acrylic acid) produced by RAFT polymerization.: Application as a very efficient dispersant of CaCO3, kaolin, and TiO2 [J].

Loiseau, J ;

Doërr, N ;

Suau, JM ;

Egraz, JB ;

Llauro, MF ;

Ladavière, C .

MACROMOLECULES, 2003, 36 (09) :3066-3077

[15] The effect of wavelength on the polymerization of multi(meth)acrylates with disulfide/benzilketal combinations [J].

Lovell, LG ;

Elliott, BJ ;

Brown, JR ;

Bowman, CN .

POLYMER, 2001, 42 (02) :421-429

[16] The direct polymerization of 2-methacryloxyethyl glucoside via aqueous reversible addition-fragmentation chain transfer (RAFT) polymerization [J].

Lowe, AB ;

Sumerlin, BS ;

McCormick, CL .

POLYMER, 2003, 44 (22) :6761-6765

[17] Aqueous RAFT polymerization: Recent developments in synthesis of functional water-soluble (Co)polymers with controlled structures [J].

McCormack, CL ;

Lowe, AB .

ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (05) :312-325

[18] Beyond inhibition:: A 1H NMR investigation of the early kinetics of RAFT-mediated polymerization with the same initiating and leaving groups [J].

McLeary, JB ;

Calitz, FM ;

McKenzie, JM ;

Tonge, MP ;

Sanderson, RD ;

Klumperman, B .

MACROMOLECULES, 2004, 37 (07) :2383-2394

[19] Synthesis of novel architectures by radical polymerization with reversible addition fragmentation chain transfer (RAFT polymerization) [J].

Moad, G ;

Mayadunne, RTA ;

Rizzardo, E ;

Skidmore, M ;

Thang, SH .

MACROMOLECULAR SYMPOSIA, 2003, 192 :1-12

[20]

Moad G, 2000, POLYM INT, V49, P993, DOI 10.1002/1097-0126(200009)49:9<993::AID-PI506>3.0.CO

← 1 2 3 4 →