Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C-H Alkylation

被引：14

作者：

Wang, Liang ^{[1
]}

Li, Zhan ^{[1
]}

Wan, Kang ^{[1
]}

Qu, Xing ^{[1
]}

Hu, Siqian ^{[1
]}

Wang, Feng ^{[2
]}

机构：

[1] Jianghan Univ, Sch Chem & Environm Engn, Minist Educ, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Peoples R China

[2] Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 432000, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 05期

基金：

中国国家自然科学基金;

关键词：

diazo compounds; transition-metal-catalysis; C-H activation; alkyaltion; N BOND FORMATION; FACILE SYNTHESIS; CARBENOID FUNCTIONALIZATION; RH(III)-CATALYZED SYNTHESIS; REGIOSELECTIVE SYNTHESIS; ROOM-TEMPERATURE; ACTIVATION; INDOLES; DERIVATIVES; COPPER;

D O I：

10.6023/cjoc201511017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diazo compounds had been widely employed as a class of environment friendly and highly efficient coupling reagents in transition-metal-catalyzed C-H bonds insertion reactions. Recently, C-H alkylation of various arenes and heteroarenes has been achieved enormous successes using diazo compounds as the alkylation reagents under a new catalytic model. The recent progress in diazo compounds mediated transition-metal-catalyzed C-H alkylation and tandem C-H alkylation/cyclization is reviewed, including reaction mechanism and synthetic applications. Furthermore, the prospects of this reaction are also discussed.

引用

页码：889 / 912

页数：24

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