Supramolecular Photothermal Effects: A Promising Mechanism for Efficient Thermal Conversion

被引：272
作者：
Zhao, Luyang [1 ]
Liu, Yamei [1 ]
Xing, Ruirui [1 ]
Yan, Xuehai [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North Second St, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, Ctr Mesosci, 1 North Second St, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 10期
基金：
中国国家自然科学基金;
关键词：
intermolecular stacking; light-harvesting species; self-assembly; Supramolecular photothermal effects; thermal energy; THERAPY; BODIPY;
D O I：
10.1002/anie.201909825
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Supramolecular assemblies have been very successful in regulating the photothermal conversion efficiency of organic photothermal materials in a simple and flexible way, compared with conventional molecular synthesis. In these assemblies, it is the inherent physiochemical mechanism that determines the photothermal conversion, rather than the assembly strategy. This Minireview summarizes supramolecular photothermal effects, which refer to the unique features of supramolecular chemistry for regulating the photothermal conversion efficiency. Emphasis is placed on the mechanisms of how self-assembly affects the photothermal performance. The supramolecular photothermal effects on various types of light-harvesting species are discussed in detail. The timely interpretation of supramolecular photothermal effects is promising for the future design of the photothermal materials with high efficiency, precision, and multiple functionalities for a wide array of applications.
引用
收藏
页码：3793 / 3801
页数：9
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