Tetraethylammonium dicopper(I) triiodide and (18-crown-6)potassium dicopper(I) triiodide

被引：13

作者：

Nurtaeva, AK ^{[1
]}

Hu, G ^{[1
]}

Holt, EM ^{[1
]}

机构：

[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197017496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraethylammonium triiododicopper(I), (C8H20N)[Cu2I3], and (18-crown-6)potassium triiododicopper(I), [K- (C12H24O6)][Cu2I3], crystallize with a polymeric series of edge-sharing Cu2I2 rhombs having Cu atoms bridged in pairs by an additional I atom, i.e. catena-poly[[copper(I)-mu(2)-iodo-copper(I)]-di-mu(3)-iodo]. The pattern of projection of bridging mu(2)-I atoms with respect to the polymeric band is up, down, up, down.

引用

页码：597 / 600

页数：4

共 9 条

[1] CRYSTAL-STRUCTURE OF TETRAMETHYLAMMONIUM CATENA-DI-MU3-IODO-[MU-IODO-DICUPRATE(I)],[N(CH3)4][CU2I3] [J].

ANDERSSON, S ;

JAGNER, S .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (03) :181-186

[2] UNUSUAL INFINITE-CHAIN ANION [CU2I3BAR]INFINITY IN THE STRUCTURE OF ITS THIOPYRILIUM SALT [J].

BATSANOV, AS ;

STRUCHKOV, YT ;

UKHIN, LY ;

DOLGOPOLOVA, NA .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 63 (01) :17-22

[3] PREPARATION AND STRUCTURE OF IODOCUPRATES(I) WITH TETRAHEDRAL FACE-TO-FACE COUPLING [J].

HARTL, H ;

MAHDJOURHASSANABADI, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (09) :772-773

[4] BIS[AQUA(15-CROWN-5)SODIUM] BIS[(15-CROWN-5)SODIUM] HEXAIODOTETRACOPPER(I) TETRAIODODICOPPER(I) [J].

HU, GZ ;

HOLT, EM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :1578-1580

[5] (15-crown-5)caesium dicopper(I) triiodide, (15-crown-5)potassium dicopper(I) triiodide and (15-crown-5)rubidium dicopper(I) triiodide [J].

Nurtaeva, AK ;

Holt, EM .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 :594-597

[6] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

[7]

SHELDRICK GM, 1993, SHELXL93 PROGR REF C

[8]

*SIEM, 1991, XSCANS US MAN

[9]

*SIEM, 1990, XP INT MOL GRAPH PRO

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