Tetraethylammonium dicopper(I) triiodide and (18-crown-6)potassium dicopper(I) triiodide

被引:13
作者
Nurtaeva, AK [1 ]
Hu, G [1 ]
Holt, EM [1 ]
机构
[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词
D O I
10.1107/S0108270197017496
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetraethylammonium triiododicopper(I), (C8H20N)[Cu2I3], and (18-crown-6)potassium triiododicopper(I), [K- (C12H24O6)][Cu2I3], crystallize with a polymeric series of edge-sharing Cu2I2 rhombs having Cu atoms bridged in pairs by an additional I atom, i.e. catena-poly[[copper(I)-mu(2)-iodo-copper(I)]-di-mu(3)-iodo]. The pattern of projection of bridging mu(2)-I atoms with respect to the polymeric band is up, down, up, down.
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收藏
页码:597 / 600
页数:4
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