Buildup of Amphiphilic Molecular Bola from Organic-Inorganic Hybrid Polyoxometalates and Their Vesicle-Like Supramolecular Assembly

被引：13

作者：

Xiao, Fengping ^{[2
]}

Misdrahi, Mauricio F. ^{[1
]}

Zhang, Jin ^{[2
]}

Yin, Panchao ^{[1
,2
]}

Hao, Jian ^{[2
]}

Lv, Chunlin ^{[2
]}

Xiao, Zicheng ^{[2
]}

Liu, Tianbo ^{[1
]}

Wei, Yonggei ^{[2
]}

机构：

[1] Lehigh Univ, Dept Chem, Bethlehem, PA 18015 USA

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 43期

关键词：

bolaamphiphiles; organic-inorganic hybrid composites; polyoxometalates; self-assembly; vesicles; ORGANOIMIDO DERIVATIVES; AROMATIC-AMINES; BOLAAMPHIPHILES; HEXAMOLYBDATE; FUNCTIONALIZATION; SURFACTANTS; NANOFIBERS; LIGANDS; BLOCKS;

D O I：

10.1002/chem.201101966

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bisarylamines with o-alkoxy substituents [o-NH 2-C 6H 4-O(CH 2) 1/2/3] 2 react with [nBu 4N] 4[α-Mo 8O 26] in anhydrous acetonitrile in the presence of N,Nâ-dicyclohexylcarbodiimide (DCC) to form a series of nanoscale molecular bola, bisorganoimido-bridged hexamolybdates with flexible alterable lengths, in which two hexamolybdate cages are connected by the bisarylimido linkers (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12006 / 12009

页数：4

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