A Sphere-in-Sphere Complex by Orthogonal Self-Assembly

被引：110

作者：

Sun, Qing-Fu ^{[1
]}

Murase, Takashi ^{[1
]}

Sato, Sota ^{[1
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 44期

基金：

日本科学技术振兴机构;

关键词：

coordination modes; entropic effects; N ligands; palladium; self-assembly; METAL-ORGANIC POLYHEDRA; BUILDING-BLOCKS; CHEMISTRY; CAPSULE; COMPONENTS;

D O I：

10.1002/anie.201104670

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Russian dolls: Two covalently tethered, curved bispyridinyl ligands and Pd II ions have been shown to self-assemble into a sphere-in-sphere complex (6.3 nm in diameter; see X-ray structure). The two ligands did not form heteroleptic mixed complexes, but instead assembled into two distinct homogeneous [M 12L 24] cuboctahedra, reminiscent of a double-shell viral capsid. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10318 / 10321

页数：4

共 27 条

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