Versatile coordination chemistry of mixed ligand silver(I) complexes of phosphanes and thioamides: Structural features and biological properties

被引：13

作者：

Ahmad, Saeed ^{[1
]}

Hanif, Muhammad ^{[2
]}

Monim-ul-Mehboob, Muhammad ^{[3
]}

Isab, Anvarhusein A. ^{[4
]}

Alotaibi, Mshari A. ^{[1
]}

Ahmad, Tayyaba ^{[5
]}

机构：

[1] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, Al Kharj 11942, Saudi Arabia

[2] Univ Auckland, Sch Chem Sci, Private Bag 92019, Auckland 1142, New Zealand

[3] Govt Coll Sci, Dept Chem, Wahdat Rd, Lahore, Pakistan

[4] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

[5] Appl Chem Res Ctr, PCSIR Labs Complex, Lahore, Pakistan

来源：

POLYHEDRON | 2022年 / 214卷

关键词：

Silver(I); Phosphanes; Thioamides; Luminescence; Crystal Structures; Antimicrobial Activity; CRYSTAL-STRUCTURE; HETEROCYCLIC THIONES; ANTIBACTERIAL ACTIVITY; TERTIARY PHOSPHINES; THIOSEMICARBAZONE CLUSTERS; ANTIMICROBIAL ACTIVITIES; LUMINESCENT PROPERTIES; MONONUCLEAR COMPLEXES; BINDING-PROPERTIES; BROMIDE COMPLEXES;

D O I：

10.1016/j.poly.2021.115643

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) complexes are of significant interest because of their potential use as an emerging class of antibiotics. This review presents a comprehensive account of the structural chemistry and biological applications of mixed ligand silver(I) complexes of phosphanes and thiones along with a brief description of the synthetic and spectroscopic aspects of the complexes. The effect of different ligands and counter ions on the structures of the complexes has been discussed. The X-ray structure analysis of these silver(I) complexes has revealed various structural types; including discrete mononuclear and dinuclear species, clusters, polymeric chains, and 3-dimensional networks. It has been observed that most of the complexes exist in mononuclear or dinuclear form, with silver atoms possessing distorted tetrahedral geometry. In rare cases Ag(I) adopts trigonal planar geometry. The multinuclear complexes often showed argentophilic (Ag-Ag) interactions. Some complexes were found to exhibit luminescent behavior. The antimicrobial and anticancer properties of the complexes are discussed in order to highlight their potential for therapeutic purposes.

引用

页数：19

共 126 条

[1] Perspectives in bioinorganic chemistry of some metal based therapeutic agents [J].

Ahmad, Saeed ;

Isab, Anvarhusein A. ;

Ali, Saqib ;

Al-Arfaj, Abdul Rahman .

POLYHEDRON, 2006, 25 (07) :1633-1645

[2] Recent studies in the coordination chemistry of heterocyclic thiones and thionates [J].

Akrivos, PD .

COORDINATION CHEMISTRY REVIEWS, 2001, 213 :181-210

[3] Cytotoxicity and Antibacterial Activity of Silver Complexes Bearing Semicarbazones and Triphenylphosphine [J].

Almeida, Vitor Y. G. ;

Rocha, Josias S. ;

Felix, Debora P. ;

Oliveira, Gabriela P. ;

Lima, Mauro A. ;

Farias, Renan L. ;

Zanetti, Renan D. ;

Netto, Adelino V. G. ;

Zambom, Carolina R. ;

Garrido, Saulo S. ;

Rocha, Fillipe, V .

CHEMISTRYSELECT, 2020, 5 (46) :14559-14563

[4] Synthesis, crystal structures, antimicrobial, antifungal and antituberculosis activities of mixed ligand silver(I) complexes [J].

Altaf, Muhammad ;

Stoeckli-Evans, Helen ;

Cuin, Alexandre ;

Sato, Daisy Nakamura ;

Pavan, Fernando Rogerio ;

Fujimura Leite, Clarice Queico ;

Ahmad, Saeed ;

Bouakka, Mohammed ;

Mimouni, Mostafa ;

Khardli, Fatima Zahra ;

Ben Hadda, Taibi .

POLYHEDRON, 2013, 62 :138-147

[5] Silver complexes with heterocyclic thioamide and tertiary arylphosphane ligands: Synthesis, crystal structures, in vitro and in silico antibacterial and cytotoxic activity, and interaction with DNA [J].

Anastasiadou, Despoina ;

Geromichalou, Elena ;

Tsavea, Eleni ;

Psomas, George ;

Hatzidimitriou, Antonios G. ;

Kalogiannis, Stavros ;

Geromichalos, George ;

Trafalis, Dimitrios ;

Dalezis, Panagiotis ;

Aslanidis, Paraskevas .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2020, 210

[6] Synthesis, spectroscopic characterization, DFT calculations and antimicrobial propetties of silver(I) complexes of 2,2′-bipyridine and 1,10-phenanthroline [J].

Aslam, Sumaira ;

Isab, Anvarhusein A. ;

Alotaibi, Mshari A. ;

Saleem, Muhammad ;

Monim-ul-Mehboob, Muhammad ;

Ahmad, Saeed ;

Georgieva, Ivelina ;

Trendafilova, Natasha .

POLYHEDRON, 2016, 115 :212-218

[7] Polymer and cage-type structures in silver(I) complexes with heterocyclic thiones and bridging diphosphine ligands.: Crystal structures of [Ag(μ-dpppent)(tHpymtH)(ONO2)]n and [Ag2(μ-trans-dppen)3(pymtH)2](NO3)2 • CH3CN [J].

Aslanidis, P ;

Divanidis, S ;

Cox, PJ ;

Karagiannidis, P .

POLYHEDRON, 2005, 24 (07) :853-863

[8] Diphosphines as bridging ligands in polymeric and dimeric thione-S-ligated Ag(I) nitrate complexes [J].

Aslanidis, P ;

Cox, PJ ;

Divanidis, S ;

Karagiannidis, P .

INORGANICA CHIMICA ACTA, 2004, 357 (09) :2677-2686

[9] Silver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands .2. Mononuclear complexes of silver(I) nitrate. The crystal structures of [Ag(PPh(3))(2)(pytH)(2)]NO3 and [Ag(PPh(3))(2)(pymtH)]NO3 [J].

Aslanidis, P ;

Karagiannidis, P ;

Akrivos, PD ;

Krebs, B ;

Lage, M .

INORGANICA CHIMICA ACTA, 1997, 254 (02) :277-284

[10] Effect of silver on burn wound infection control and healing: Review of the literature [J].

Atiyeh, Bishara S. ;

Costagliola, Michel ;

Hayek, Shady N. ;

Dibo, Saad A. .

BURNS, 2007, 33 (02) :139-148

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