Synthesis, Crystal Structure and Thermal Behavior of a New Polynitrile N,N,N',N'-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine

被引：1

作者：

Xu, Rui-Bo ^{[2
,3
]}

Xu, Xing-You ^{[1
,3
]}

Zhou, Yu-Min ^{[2
]}

Yang, Xu-Jie ^{[3
]}

Ma, Wei-Xing ^{[2
]}

Wang, Da-Qi ^{[4
]}

Huang, Yu-Ping ^{[2
]}

Xu, Chun-Mei ^{[2
]}

机构：

[1] Huaiyin Inst Technol, Huaian 223003, Peoples R China

[2] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Peoples R China

[3] Nanjing Univ Sci & Technol, Minist Educ, Lab Soft Chem & Funct Mat, Nanjing 210094, Peoples R China

[4] Shandong Liaocheng Univ, Dept Chem Engn, Liaocheng 252059, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 08期

关键词：

Polynitrile; N,N,N ',N '-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine; Synthesis; Crystal structure; Thermal behavior; ANTITUMOR-ACTIVITY; AMINES;

D O I：

10.1007/s10870-011-0069-8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new polynitrile, N,N,N',N'-tetra(2-cyanoethyl)-1,4-bis(3-aminopropyl)piperazine, was synthesized by the nucleophilic addition reaction of 1,4-bis(3-aminopropyl)piperazine and acrylonitrile for the first time. The title compound was characterized by elemental analysis, IR spectrum, and its crystal structure determined by X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system with space group P2 (1)/c and a = 8.6195(12), b = 9.300(14), c = 16.221(2) , beta = 97.824(2)A degrees, V = 1288.2(3) (3), D (c) = 1.064 g cm(-3), M (r) = 412.59, Z = 2, F(000) = 448, mu = 0.067 mm(-1). The TG-DTA analysis revealed that the title compound possesses relatively good thermal stability under 220 A degrees C.

引用

页码：1190 / 1194

页数：5

共 18 条

[1] Ruthenium N-heterocyclic carbene catalysts for selective reduction of nitriles to primary amines [J].

Addis, Daniele ;

Enthaler, Stephan ;

Junge, Kathrin ;

Wendt, Bianca ;

Beller, Matthias .

TETRAHEDRON LETTERS, 2009, 50 (26) :3654-3656

[2] One-pot synthesis of tripodal tris(2-aminoethyl)amine derivatives from seven molecular components [J].

Almesaker, Ann ;

Scott, Janet L. ;

Spiccia, Leone ;

Strauss, Christopher R. .

TETRAHEDRON LETTERS, 2009, 50 (16) :1847-1850

[3]

GAO J, 2003, IND MIN PROCESS, V2, P23

[4]

GAO J, 2003, J HUAIHAI I TECHNOL, V12, P39

[5]

[高健 Gao Jian], 2003, [现代化工, Modern Chemical Industry], V23, P32

[6]

[高健 Gao Jian], 2005, [化学试剂, Chemical Reagents], V27, P173

[7] Synthesis and antitumor activity of water-soluble poly(aminoheterocyclic amine)s (I):: N,N,N′,N′-tetra[2-(4-amino-5-substituted-s-triazol-3-yl sulfanyl)ethyl]-1,4-benzyldiamine salts [J].

Hu, Guo Qiang ;

Xie, Song Qiang ;

Huang, Wen Long .

CHINESE CHEMICAL LETTERS, 2007, 18 (02) :124-126

[8] Direct oxidative conversion of alcohols and amines to nitriles with molecular iodine and DIH in aq NH3 [J].

Iida, Shinpei ;

Togo, Hideo .

TETRAHEDRON, 2007, 63 (34) :8274-8281

[9]

[金义翠 Jin Yicui], 2005, [化学试剂, Chemical Reagents], V27, P485

[10]

[聂国朝 Nie Guozhao], 2004, [感光科学与光化学, Photographic Science and Photochemistry], V22, P293

← 1 2 →