Solvent friction effect on intramolecular electron transfer

被引：21

作者：

Liu, M

Ito, N

Maroncelli, M ^{[1
]}

Waldeck, DH

Oliver, AM

Paddon-Row, MN

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[2] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

[3] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 50期

关键词：

D O I：

10.1021/ja055596a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

U-shaped donor-bridge-acceptor molecules with different electronic couplings have been investigated as a function of temperature in solvents with slow polarization relaxation, in particular, N-methylacetamide (NMA) and N-methylpropionamide (NMP). At high temperature, the electron-transfer rate is well described by a nonadiabatic model; however, the rate at low temperature is controlled by the solvent friction. The change of the electron-transfer mechanism is discussed and compared with theoretical models.

引用

页码：17867 / 17876

页数：10

共 30 条

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