Au/Ag-Mo nano-rods catalyzed reductive coupling of nitrobenzenes and alcohols using glycerol as the hydrogen source

被引：61

作者：

Cui, Xinjiang ^{[1
,2
]}

Zhang, Chengming ^{[1
,2
]}

Shi, Feng ^{[1
]}

Deng, Youquan ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 75期

基金：

中国国家自然科学基金;

关键词：

SUPPORTED RUTHENIUM HYDROXIDE; SELECTIVE N-ALKYLATION; BORROWING HYDROGEN; INTRAMOLECULAR HYDROAMINATION; UNACTIVATED ALKENES; EFFICIENT SYNTHESIS; GOLD NANOCLUSTERS; AMINE FORMATION; ACTIVE GOLD; OXIDATION;

D O I：

10.1039/c2cc34178f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient Au/Ag-Mo nano-rods catalyst was prepared for the one-pot synthesis of imine and amine using equal molar ratio of nitrobenzene and alcohol as starting materials, and bio-based glycerol as the hydrogen source. The reaction mechanism of the nitrobenzene reduction, amine and aldehyde coupling, and imine reduction was explored.

引用

页码：9391 / 9393

页数：3

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