Au/Ag-Mo nano-rods catalyzed reductive coupling of nitrobenzenes and alcohols using glycerol as the hydrogen source

被引：61

作者：

Cui, Xinjiang ^{[1
,2
]}

Zhang, Chengming ^{[1
,2
]}

Shi, Feng ^{[1
]}

Deng, Youquan ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 75期

基金：

中国国家自然科学基金;

关键词：

SUPPORTED RUTHENIUM HYDROXIDE; SELECTIVE N-ALKYLATION; BORROWING HYDROGEN; INTRAMOLECULAR HYDROAMINATION; UNACTIVATED ALKENES; EFFICIENT SYNTHESIS; GOLD NANOCLUSTERS; AMINE FORMATION; ACTIVE GOLD; OXIDATION;

D O I：

10.1039/c2cc34178f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient Au/Ag-Mo nano-rods catalyst was prepared for the one-pot synthesis of imine and amine using equal molar ratio of nitrobenzene and alcohol as starting materials, and bio-based glycerol as the hydrogen source. The reaction mechanism of the nitrobenzene reduction, amine and aldehyde coupling, and imine reduction was explored.

引用

页码：9391 / 9393

页数：3

共 44 条

[1] Amines made easily: A highly selective hydroaminomethylation of olefins [J].

Ahmed, M ;

Seayad, AM ;

Jackstell, R ;

Beller, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10311-10318

[2] The Catalytic Amination of Alcohols [J].

Baehn, Sebastian ;

Imm, Sebastian ;

Neubert, Lorenz ;

Zhang, Min ;

Neumann, Helfried ;

Beller, Matthias .

CHEMCATCHEM, 2011, 3 (12) :1853-1864

[3] In situ oxidation-imine formation-reduction routes from alcohols to amines [J].

Blackburn, L ;

Taylor, RJK .

ORGANIC LETTERS, 2001, 3 (11) :1637-1639

[4] Impregnated Ruthenium on Magnetite as a Recyclable Catalyst for the N-Alkylation of Amines, Sulfonamides, Sulfinamides, and Nitroarenes Using Alcohols as Electrophiles by a Hydrogen Autotransfer Process [J].

Cano, Rafael ;

Ramon, Diego J. ;

Yus, Miguel .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (14) :5547-5557

[5] The structure of catalytically active gold on titania [J].

Chen, MS ;

Goodman, DW .

SCIENCE, 2004, 306 (5694) :252-255

[6] A Bifunctional Pd/MgO Solid Catalyst for the One-Pot Selective N-Monoalkylation of Amines with Alcohols [J].

Corma, Avelino ;

Rodenas, Tania ;

Sabater, Maria J. .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (01) :254-260

[7] Selective oxidation using gold [J].

Della Pina, Cristina ;

Falletta, Ermelinda ;

Prati, Laura ;

Rossi, Michele .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) :2077-2095

[8] Ruthenium-Catalyzed Tertiary Amine Formation from Nitroarenes and Alcohols [J].

Feng, Chao ;

Liu, Yong ;

Peng, Shengming ;

Shuai, Qi ;

Deng, Guojun ;

Li, Chao-Jun .

ORGANIC LETTERS, 2010, 12 (21) :4888-4891

[9] Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles [J].

Guillena, Gabriela ;

Ramon, Diego J. ;

Yus, Miguel .

CHEMICAL REVIEWS, 2010, 110 (03) :1611-1641

[10] Efficient Iron-Catalyzed N-Arylation of Aryl Halides with Amines [J].

Guo, Diliang ;

Huang, He ;

Xu, Jinyi ;

Jiang, Hualiang ;

Liu, Hong .

ORGANIC LETTERS, 2008, 10 (20) :4513-4516

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