Catalytic decarboxylation of petroleum acids from high acid crude oils over solid acid catalysts

被引：37

作者：

Fu, Xiaoqin ^{[1
]}

Dai, Zhenyu ^{[2
]}

Tian, Songbai ^{[2
]}

Long, Jun ^{[2
]}

Hou, Suandi ^{[2
]}

Wang, Xieqing ^{[2
]}

机构：

[1] Environm Monitoring Ctr Ningbo, Ningbo, Zhejiang, Peoples R China

[2] Res Inst Petr Proc, Beijing, Peoples R China

来源：

ENERGY & FUELS | 2008年 / 22卷 / 03期

关键词：

D O I：

10.1021/ef7006547

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The presence of petroleum acids in crude oils is a key problem in refineries due to corrosion to industrial units. To economically and effectively remove the petroleum acids from high acid crude oils is an urgent project. A theoretical and experimental study to develop a catalytic decarboxylation process to remove petroleum acids from high acid crude oils was conducted. By using the molecular simulation technology, a solid acid catalyst was constructed for removing petroleum acids. The experimental results indicated that the acid removal rate of a high acid crude oil with a total acid number (TAN) of 12.52 over the solid acid catalyst of MLC500 was up to 97% at a volume space velocity of 8 h(-1), ratio of catalyst to oil of 7.5, and temperature of 460 degrees C in the fixed fluid bed reactor.

引用

页码：1923 / 1929

页数：7

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