The photodegradation of methylene blue in water with PVDF/GO/ZnO composite membrane

被引：111

作者：

Zhang, Dongdong ^{[1
]}

Dai, Fengying ^{[1
]}

Zhang, Ping ^{[1
]}

An, Zihan ^{[1
]}

Zhao, Yiping ^{[1
]}

Chen, Li ^{[1
,2
]}

机构：

[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China

[2] Tianjin Univ Technol, Sch Mat Sci & Engn, Tianjin 300384, Peoples R China

来源：

MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2019年 / 96卷

基金：

中国国家自然科学基金;

关键词：

PVDF; ZnO; GO; Photodegradation; MB; PHOTOCATALYTIC ACTIVITY; GRAPHENE OXIDE; VISIBLE-LIGHT; MECHANICAL-PROPERTIES; ZNO NANOPARTICLES; DEGRADATION; PERFORMANCE; ADSORPTION; DYES; HYDROPHILICITY;

D O I：

10.1016/j.msec.2018.11.049

中图分类号：

TB3 [工程材料学]; R318.08 [生物材料学];

学科分类号：

0805 ; 080501 ; 080502 ;

摘要：

The immobilization of photo-catalyst can effectively avoid the difficulty in recovery of the nano-catalysts after photo-degradation. In this work, PVDF/GO/ZnO composite membranes with photocatalytic performance for organic dyes were prepared by using zinc oxide (ZnO) as photo-catalyst, graphene (GO) as dispersant and poly (vinylidene fluoride) (PVDF) membrane as carrier. The effect ZnO and GO on the structure, surface composition and photocatalytic activity of PVDF/GO/ZnO composite membranes were investigated. Owing to the strong hydrophilicity of the carboxyl group, the addition of GO enhanced the dispersibility of ZnO in PVDF membranes, which was proved by SEM results. Under Xenon irradiation (300 W), the photocatalytic degradation rate of PVDF/GO/ZnO composite membranes for methylene blue (MB) could reach 86.84%. Furthermore, the photo-catalytic efficiency of the composites membrane for MB was evaluated with different initial concentrations of MB, pH value of the solution, and electron trapping agent-H2O2 content. And the radical trapping experiments with different active radical scavengers showed that the oxidizing species (center dot O-2(-)) plays an important role in the decolorization process of MB. In summary, this work provides an efficient method to improve the photo-degradability of PVDF/GO/ZnO composite membranes and has great potential in the field of water purification.

引用

页码：684 / 692

页数：9

共 43 条

[21] Synthesis, structural and optical properties of ZnO spindle/reduced graphene oxide composites with enhanced photocatalytic activity under visible light irradiation [J].

Prabhu, S. ;

Pudukudy, M. ;

Sohila, S. ;

Harish, S. ;

Navaneethan, M. ;

Navaneethan, D. ;

Ramesh, R. ;

Hayakawa, Y. .

OPTICAL MATERIALS, 2018, 79 :186-195

[22] Statistical and equilibrium studies on enhancing biosorption capacity of Saccharomyces cerevisiae through acid treatment [J].

Pratibha, R. ;

Malar, P. ;

Rajapriya, T. ;

Balapoornima, S. ;

Ponnusami, V. .

DESALINATION, 2010, 264 (1-2) :102-107

[23] Synthesis, characterization and photocatalytic activity of annealing dependent quasi spherical and capsule like ZnO nanostructures [J].

Pudukudy, Manoj ;

Hetieqa, Ain ;

Yaakob, Zahira .

APPLIED SURFACE SCIENCE, 2014, 319 :221-229

[24] Simple chemical synthesis of novel ZnO nanostructures: Role of counter ions [J].

Pudukudy, Manoj ;

Yaakob, Zahira .

SOLID STATE SCIENCES, 2014, 30 :78-88

[25] Facile solid state synthesis of ZnO hexagonal nanogranules with excellent photocatalytic activity [J].

Pudukudy, Manoj ;

Yaakob, Zahira .

APPLIED SURFACE SCIENCE, 2014, 292 :520-530

[26] Hydrothermal synthesis of mesostructured ZnO micropyramids with enhanced photocatalytic performance [J].

Pudukudy, Manoj ;

Yaakob, Zahira .

SUPERLATTICES AND MICROSTRUCTURES, 2013, 63 :47-57

[27] Photocatalytic decomposition of dyes using ZnO doped SnO2 nanoparticles prepared by solvothermal method [J].

Rashad, Mohamed M. ;

Ismail, Adel A. ;

Osama, I. ;

Ibrahim, I. A. ;

Kandil, Abdel-Hakim T. .

ARABIAN JOURNAL OF CHEMISTRY, 2014, 7 (01) :71-77

[28] Enhancement of photocatalytic activity by semiconductor heterojunctions:: α-Fe2O3, WO3 and CdS deposited on ZnO [J].

Sakthivel, S ;

Geissen, SU ;

Bahnemann, DW ;

Murugesan, V ;

Vogelpohl, A .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :283-293

[29] Investigation of the Local Structure of Graphene Oxide [J].

Saxena, Sumit ;

Tyson, Trevor A. ;

Negusset, Ezana .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (24) :3433-3437

[30] Adsorption of methylene blue onto jute fiber carbon: kinetics and equilibrium studies [J].

Senthilkumaar, S ;

Varadarajan, PR ;

Porkodi, K ;

Subbhuraam, C .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 284 (01) :78-82

← 1 2 3 4 5 →