TG-FTIR-MS (Evolved Gas Analysis) of bidi tobacco powder during combustion and pyrolysis

被引:65
作者
Ahamad, Tansir [1 ]
Alshehri, Saad M. [1 ]
机构
[1] King Saud Univ, Dept Chem, Riyadh 11451, Saudi Arabia
关键词
Indian bidi; TG/FTIR/MS; Tobacco; Cancer; Nicotine; FLIGHT MASS-SPECTROMETRY; PHOTOIONIZATION METHODS; CHEMICAL-CONSTITUENTS; MAINSTREAM SMOKE; CIGARETTE; FORMALDEHYDE; VIRGINIA; CADMIUM; CANCER; BURLEY;
D O I
10.1016/j.jhazmat.2011.10.090
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Bidi smoke, a complex mixture of toxic and carcinogens chemicals causes a large and growing number of premature deaths in South Asian countries especially in India and Bangladesh. The evolved products during the thermal degradation of bidi tobacco powder (BTP) have been measured by using TG-FrIR-MS technique. The results revealed that the main gases and volatile products released during the combustion and pyrolysis of BTP are CO, CO2, NH3, HCN, NO, isoprene, formaldehyde, acetaldehyde, acrolein, etc. Still others such as nicotine, phenol, polyaromatic hydrocarbon and some tobacco specific nitrosamines are contained in submicron sized solid particles that are suspended in Bidi smoke. The intensity or the quantity of evolved products is higher during the combustion than pyrolysis of BTP. The evolved chemical data suggest that Bidi smoke is responsible for cancer of the throat, oral cavity, pharynx, larynx, lungs, esophagus, stomach, and liver. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:200 / 208
页数:9
相关论文
共 43 条
[1]   Application of time-of-flight mass spectrometry with laser-based photoionization methods for analytical pyrolysis of PVC and tobacco [J].
Adam, T ;
Streibel, T ;
Mitschke, S ;
Mühlberger, F ;
Baker, RR ;
Zimmermann, R .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2005, 74 (1-2) :454-464
[2]   Discrimination of three tobacco types (Burley, Virginia and Oriental) by pyrolysis single-photon ionisation-time-of-flight mass spectrometry and advanced statistical methods [J].
Adam, T ;
Ferge, T ;
Mitschke, S ;
Streibel, T ;
Baker, RR ;
Zimmermann, R .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2005, 381 (02) :487-499
[3]   Puff-by-puff resolved characterisation of cigarette mainstream smoke by single photon ionisation (SPI)-time-of-flight mass spectrometry (TOFMS): Comparison of the 2R4F research cigarette and pure Burley, Virginia, Oriental and Maryland tobacco cigarettes [J].
Adam, Thomas ;
Mitschke, Stefan ;
Streibel, Thorsten ;
Baker, Richard R. ;
Zimmermann, Ralf .
ANALYTICA CHIMICA ACTA, 2006, 572 (02) :219-229
[4]   RESIDUAL METAL CONCENTRATIONS IN SOILS AND LEAF ACCUMULATIONS IN TOBACCO A DECADE FOLLOWING FARMLAND APPLICATION OF MUNICIPAL SLUDGE [J].
ADAMU, CA ;
BELL, PF ;
MULCHI, C ;
CHANEY, R .
ENVIRONMENTAL POLLUTION, 1989, 56 (02) :113-126
[5]   Thermal degradation and evolved gas analysis of thiourea-formaldehyde resin (TFR) during pyrolysis and combustion [J].
Ahamad, Tansir ;
Alshehri, Saad M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 109 (02) :1039-1047
[6]  
[Anonymous], BEITR TABAKFORSCH, DOI DOI 10.2478/CTTR-2013-0377
[7]  
[Anonymous], 1999, MMWR-MORBID MORTAL W, V48, P796
[8]   CADMIUM AND NICKEL IN MAINSTREAM PARTICULATES OF CIGARETTES CONTAINING TOBACCO GROWN ON A LOW-CADMIUM SOIL-SLUDGE MIXTURE [J].
BACHE, CA ;
LISK, DJ ;
DOSS, GJ ;
HOFFMANN, D ;
ADAMS, JD .
JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH, 1985, 16 (3-4) :547-552
[9]   An overview of the effects of tobacco ingredients on smoke chemistry and toxicity [J].
Baker, RR ;
Massey, ED ;
Smith, G .
FOOD AND CHEMICAL TOXICOLOGY, 2004, 42 :S53-S83
[10]   Gas- and particulate-phase specific tracer and toxic organic compounds in environmental tobacco smoke [J].
Bi, XH ;
Sheng, GY ;
Feng, YL ;
Fu, JM ;
Xie, JX .
CHEMOSPHERE, 2005, 61 (10) :1512-1522