Synthesis of novel O,P,C-Cage complexes via thermal c-o ring opening of an oxaphosphirane W(CO)5 complex

被引:22
作者
Bode, Maren [1 ]
Schnakenburg, Gregor [1 ]
Jones, Peter G. [2 ]
Streubel, Rainer [1 ]
机构
[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
关键词
D O I
10.1021/om7012953
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A facile and highly stereoselective synthesis of novel O,P,C-cage complexes via thermal C-O ring opening of an oxaphosphirane W(CO)(5) complex is described. All compounds were unambiguously characterized by elemental analysis, multinuclear NMR, IR, MS, and single-crystal X-ray diffraction studies.
引用
收藏
页码:2664 / 2667
页数:4
相关论文
共 40 条
[1]   OXASILACYCLOPROPANE - ISOLATION AND CHARACTERIZATION [J].
ANDO, W ;
HAMADA, Y ;
SEKIGUCHI, A ;
UENO, K .
TETRAHEDRON LETTERS, 1982, 23 (50) :5323-5326
[2]   EVIDENCE OF FORMATION OF OXASILACYCLOPROPANE FROM REACTION OF SILYLENE WITH KETONE [J].
ANDO, W ;
IKENO, M ;
SEKIGUCHI, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (19) :6447-6449
[3]   A STUDY OF THE POLARITIES, ANISOTROPIC POLARIZABILITIES AND CARBONYL INFRARED VIBRATIONAL FREQUENCIES OF THE COMPLEXES [M(CO)5(P(OCH2)3CME)] (M = CR, MO OR W) AND THE CRYSTAL-STRUCTURE OF [MO(CO)5(P(OCH2)3CME)] - EVIDENCE FOR PI-ACCEPTOR BEHAVIOR IN COORDINATED PHOSPHORUS [J].
ARONEY, MJ ;
DAVIES, MS ;
HAMBLEY, TW ;
PIERENS, RK .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (01) :91-96
[4]   EPOXIDATION OF THE P=C DOUBLE-BOND OF PHOSPHAALKENE COMPLEXES - X-RAY CRYSTAL-STRUCTURE ANALYSIS OF A STABLE OXAPHOSPHIRANE COMPLEX [J].
BAUER, S ;
MARINETTI, A ;
RICARD, L ;
MATHEY, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (10) :1166-1167
[5]  
Bauer S., 1990, ANGEW CHEM, V102, P1188, DOI DOI 10.1002/ANGE.19901021026
[6]  
BODE M, THESIS U BONN
[7]   Synthesis of the first 1,3,4λ3-dioxaphospholane complexes [J].
Bode, Maren ;
Nieger, Martin ;
Streubel, Rainer .
ORGANOMETALLICS, 2007, 26 (01) :245-246
[8]   A study of NMR chemical shielding in 5-coordinate phosphorus compounds (phosphoranes) [J].
Chesnut, DB ;
Quin, LD .
TETRAHEDRON, 2005, 61 (52) :12343-12349
[9]  
Coates G. W., 2004, ANGEW CHEM, V116, P6784, DOI DOI 10.1002/ANGE.200460442
[10]   Discrete metal-based catalysts for the copolymerization CO2 and epoxides:: Discovery, reactivity, optimization, and mechanism [J].
Coates, GW ;
Moore, DR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (48) :6618-6639