Quantum-Chemical Modeling of the Ion Associates in the [Co(NH3)6]3+-Cl- System

被引：0

作者：

Gorel'skii, S. I. ^{[1
]}

Kotov, V. Yu.

机构：

[1] Univ York, Toronto, ON, Canada

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1998年 / 24卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electronic absorption spectra of the ion associates [Co(NH(3))(6)](3+), mCl(-) are calculated and analyzed. The positions of the outer-sphere charge-transfer bands are shown to be mainly determined by the Coulomb interaction between the ions and the solvate environment. The intensities of these electronic transitions depend on the mutual orientation of ions.

引用

页码：491 / 494

页数：4

共 23 条

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