Aggregation-induced emission in BF2-hydrazone (BODIHY) complexes

被引：189
作者：
Yang, Yin [1 ]
Su, Xin [1 ]
Carroll, Calden N. [2 ,3 ]
Aprahamian, Ivan [1 ]
机构：
[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA
[2] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
[3] Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA
来源：
CHEMICAL SCIENCE | 2012年 / 3卷 / 02期
关键词：
EFFICIENT ENERGY-TRANSFER; SOLID-STATE; CONJUGATED POLYMERS; PHOTOLUMINESCENCE; DERIVATIVES; DYES; INHIBITION; CHEMISTRY; MECHANISM; DEVICES;
D O I：
10.1039/c1sc00658d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new family of BF2-hydrazone complexes was developed that exhibit enhanced emission in the solid-state. The modularity of the systems enabled their structure-property analysis, which showed that the solid-state fluorescence quantum yield is dependent on the molecule's planarity, dipole moment and number of pi-pi interactions it forms. One of the BF2-hydrazone complexes was easily transformed into a solid-state acid/base sensor.
引用
收藏
页码：610 / 613
页数：4
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