Co2Mo3O8/Co3O4 micro-flowers architectured material for high-performance supercapacitor electrodes

被引:14
作者
Ankinapalli, Obula Reddy [1 ]
Krishna, B. N. Vamsi [1 ]
Hua, Yongbin [1 ]
Yu, Jae Su [1 ]
机构
[1] Kyung Hee Univ, Inst Wearable Convergence Elect, Dept Elect & Informat Convergence Engn, Yongin 17104, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Transition metal oxides; Co2Mo3O8/Co3O4 (CMO/CO) micro-flower-like architectures; Electrochemical properties; Asymmetric supercapacitors; REDUCED GRAPHENE OXIDE; ENERGY-STORAGE; ARRAYS; HETEROSTRUCTURES; CAPACITANCE; FOAM;
D O I
10.1016/j.jallcom.2022.167063
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Engineering novel nano/microarchitectures has attracted great attention because they can provide conductive, morphological, and remarkable electrochemical properties in energy storage and energy conversion fields. Herein, the Co2Mo3O8/Co3O4 (CMO/CO) micro-flower-like architectures were prepared via a simple one-step hydrothermal technique. The CMO/CO-based electrode samples were investigated at different reaction temperatures of 120, 150, and 180 ?. The prepared CMO/CO-150 material revealed a large specific surface area (108.57 m(2) g(-1)). The excellent specific capacity value of 301 mAh g(-1) (2142 F g(-1)) at 1 A g(-1) of current density was obtained by the optimized CMO/CO-150 sample. Moreover, after successfully performing 5000 cycles at 20 mA cm(-2), the CMO/CO electrode represented a capacity retention of 92% with 99% coulombic efficiency. Additionally, the designed pouch-like asymmetric supercapacitor (ASC) with the optimized CMO/CO-150 material and activated carbon material delivered high energy and power density values of 34.38 Wh kg(-1) and 2987.07 W kg(-1), respectively. For testing practical applications, the fabricated ASC device was also employed to power portable electronic devices. Consequently, the achieved outstanding electrochemical results suggest that CMO/CO electrodes are favorable material for energy storage applications. (c) 2022 Elsevier B.V. All rights reserved.
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页数:11
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