Molecular design of new organic sensitizers based on thieno[1,4]benzothiazine for dye-sensitized solar cells

被引:6
作者
Liu, Hu [1 ]
Liao, Xingrong [1 ]
Li, Xiaoyu [1 ]
Wu, Di [1 ]
Guo, Qiang [1 ]
Wu, Jie [1 ]
Qian, Shengyou [1 ]
Lan, Jingbo [1 ]
Wang, Ruilin [2 ]
You, Jingsong [1 ]
机构
[1] Sichuan Univ, West China Med Sch, State Key Lab Biotherapy, Minist Educ,Coll Chem,Key Lab Green Chem & Techno, Chengdu 610064, Peoples R China
[2] Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610064, Peoples R China
关键词
PHENOTHIAZINE-BASED DYES; PHOTOVOLTAIC PERFORMANCE; DOUBLE ANCHORS; TIO2; FILMS; PI-LINKER;
D O I
10.1039/c5ra07785k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel thieno[1,4]benzothiazine donor has been developed for the first time to construct metal-free organic sensitizers, which exhibit more dramatically red-shifted absorptions than phenothiazine-based dyes. Under AM 1.5G irradiation, the conversion efficiency of the new dye TBT-1-based DSSC (eta = 7.6%) approximates to that of the phenothiazine-based PT-C-6, indicating thieno[1,4]benzothiazine would be a promising electron donor for the construction of organic optoelectronic materials.
引用
收藏
页码:56865 / 56871
页数:7
相关论文
共 34 条
[1]   Metal free sensitizer and catalyst for dye sensitized solar cells [J].
Ahmad, Shahzada ;
Guillen, Elena ;
Kavan, Ladislav ;
Graetzel, Michael ;
Nazeeruddin, Mohammad K. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (12) :3439-3466
[2]   Organic dye-sensitized solar cells with a cobalt redox couple: influences of π-linker rigidification and dye-bath solvent selection [J].
Cai, Ning ;
Li, Renzhi ;
Wang, Yinglin ;
Zhang, Min ;
Wang, Peng .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (01) :139-147
[3]   Highly efficient triarylene conjugated dyes for sensitized solar cells [J].
Chang, Yuan Jay ;
Chow, Tahsin J. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (26) :9523-9531
[4]   Sensitizer molecular structure-device efficiency relationship in dye sensitized solar cells [J].
Clifford, John N. ;
Martinez-Ferrero, Eugenia ;
Viterisi, Aurelien ;
Palomares, Emilio .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1635-1646
[5]   Incorporating Benzotriazole Moiety to Construct D-A-π-A Organic Sensitizers for Solar Cells: Significant Enhancement of Open-Circuit Photovoltage with Long Alkyl Group [J].
Cui, Yan ;
Wu, Yongzhen ;
Lu, Xuefeng ;
Zhang, Xi ;
Zhou, Gang ;
Miapeh, Fohn B. ;
Zhu, Weihong ;
Wang, Zhong-Sheng .
CHEMISTRY OF MATERIALS, 2011, 23 (19) :4394-4401
[6]   CuI-catalyzed coupling reactions of aryl iodides and bromides with thiols promoted by amino acid ligands [J].
Deng, W ;
Zou, Y ;
Wang, YF ;
Liu, L ;
Guo, QX .
SYNLETT, 2004, (07) :1254-1258
[7]   Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells [J].
Gao, Feifei ;
Wang, Yuan ;
Shi, Dong ;
Zhang, Jing ;
Wang, Mingkui ;
Jing, Xiaoyan ;
Humphry-Baker, Robin ;
Wang, Peng ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10720-10728
[8]   Dye-Sensitized Solar Cells [J].
Hagfeldt, Anders ;
Boschloo, Gerrit ;
Sun, Licheng ;
Kloo, Lars ;
Pettersson, Henrik .
CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663
[9]   Efficient near infrared D-π-A sensitizers with lateral anchoring group for dye-sensitized solar cells [J].
Hao, Yan ;
Yang, Xichuan ;
Cong, Jiayan ;
Tian, Haining ;
Hagfeldt, Anders ;
Sun, Licheng .
CHEMICAL COMMUNICATIONS, 2009, (27) :4031-4033
[10]   Effect of additives on the photovoltaic performance of coumarin-dye-sensitized nanocrystalline TiO2 solar cells [J].
Hara, K ;
Dan-Oh, Y ;
Kasada, C ;
Ohga, Y ;
Shinpo, A ;
Suga, S ;
Sayama, K ;
Arakawa, H .
LANGMUIR, 2004, 20 (10) :4205-4210