The first example of 1,3-dipolar cycloaddition reactions of nitrones to vinylidenecyclopropanes

被引：13
作者：
Larina, Anna G. [1 ]
Stepakov, Alexander V. [1 ]
Boitsov, Vitaly M. [2 ]
Molchanov, Alexander P. [1 ]
Gurzhiy, Vladislav V. [1 ]
Starova, Galina L. [1 ]
Lykholay, Anna N. [3 ]
机构：
[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia
[2] St Petersburg Acad Univ, Nanotechnol Res & Educ Ctr RAS, St Petersburg 195220, Russia
[3] St Petersburg State Univ, Dept Biol, St Petersburg 199034, Russia
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 44期
关键词：
Vinylidenecyclopropanes; Nitrones; 4-Cyclopropylidene-isoxazolidines; 1,3-Dipolar cycloaddition; ACID-CATALYZED REARRANGEMENT; UNIQUE TETRASUBSTITUTED ALKENE; FACILE SYNTHETIC PROTOCOL; DIPOLAR CYCLOADDITION; BUILDING-BLOCKS; INTRAMOLECULAR REARRANGEMENT; VINYLIDENE-CYCLOPROPANES; CASCADE REACTIONS; LEWIS; ARYLVINYLIDENECYCLOPROPANES;
D O I：
10.1016/j.tetlet.2011.08.116
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first example of 1,3-dipolar cycloaddition reactions of nitrones to vinylidenecyclopropanes is described. The nitrones react with the C1'-C2' double bond of vinylidenecyclopropanes to give the corresponding 4-cyclopropylidene-isoxazolidines in moderate yields. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
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页码：5777 / 5781
页数：5
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