A luminescent dinuclear cadmium(II) supramolecular architecture constructed from a metal-organic synthon

被引：8

作者：

Zhang, Guoqi ^{[1
]}

Ma, Jinshi ^{[1
]}

Yang, Guoqiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100080, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2011年 / 1004卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

Metal-organic synthon; Supramolecular architecture; Hydrothermal synthesis; Photoluminescence; ENERGY-TRANSFER; SILVER-NITRATE; FLUORESCENCE; FRAMEWORK; LIGAND; COMPLEXES; POLYMERS; ELECTRON; SYSTEMS;

D O I：

10.1016/j.molstruc.2011.08.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A dinuclear cadmium(II) supramolecular complex containing a 9,10-anthraquinone-2,6-disulfonate chromophore was synthesized hydrothermally by using a mononuclear metal-organic synthon Cd(phen)(2) (NO3)(2), 1, where phen is 1,10-phenanthroline. The compound was characterized by microanalysis, IR spectrum, thermogramic analysis and X-ray crystallography. The crystal structure exhibits a novel dinuclear supramolecular architecture based on Cd(phen)(2) bridged with 9,10-anthraquinone-2,6-disulfonate (ads). Both intra and intermolecular hydrogen bonds contribute to extend the dinuclear assay to a two-dimensional (2D) network. Photoluminescence property has been measured in the solid state at ambient temperature. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：248 / 251

页数：4

共 38 条

[1]

Balzani V.S. F., 1991, Supramolecular Photochemistry

[2] ELECTRONIC-ENERGY TRANSFER IN A SUPRAMOLECULAR SPECIES CONTAINING THE [RU(BPY)(3)](2+), [OS(BPY)(3)](2+), AND ANTHRACENE CHROMOPHORIC UNITS [J].

BELSER, P ;

DUX, R ;

BAAK, M ;

DECOLA, L ;

BALZANI, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (05) :595-598

[3] Metal-induced self-assembly of a pyrene-tethered hydroxamate ligand for the generation of multichromophoric supramolecular systems. The pyrene excimer as switch for iron(III)-driven intramolecular fluorescence quenching [J].

Bodenant, B ;

Fages, F ;

Delville, MH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (30) :7511-7519

[4] INTRAMOLECULAR ENERGY-TRANSFER IN A CHROMOPHORE QUENCHER COMPLEX [J].

BOYDE, S ;

STROUSE, GF ;

JONES, WE ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7448-7454

[5] A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates [J].

Cai, JW ;

Chen, CH ;

Feng, XL ;

Liao, CZ ;

Chen, XM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (16) :2370-2375

[6] A luminescent microporous metal-organic framework for the recognition and sensing of anions [J].

Chen, Banglin ;

Wang, Liangbo ;

Zapata, Fatima ;

Qian, Guodong ;

Lobkovsky, Emil B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) :6718-+

[7] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].

Chen, Banglin ;

Zhao, Xuebo ;

Putkham, Apipong ;

Hong, Kunlun ;

Lobkovsky, Emil B. ;

Hurtado, Eric J. ;

Fletcher, Ashleigh J. ;

Thomas, K. Mark .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423

[8] Variation in the coordination mode of arenedisulfonates: Syntheses and structural characterization of mononuclear and dinuclear cadmium(II) arenedisulfonate complexes with two- to zero-dimensional architectures [J].

Chen, CH ;

Cai, JW ;

Liao, CZ ;

Feng, XL ;

Chen, XM ;

Ng, SW .

INORGANIC CHEMISTRY, 2002, 41 (19) :4967-4974

[9] Enantioselective catalysts for the Henry reaction: fine-tuning the catalytic components [J].

Constable, Edwin C. ;

Zhang, Guoqi ;

Housecroft, Catherine E. ;

Neuburger, Markus ;

Schaffner, Silvia ;

Woggon, Wolf-D. ;

Zampese, Jennifer A. .

NEW JOURNAL OF CHEMISTRY, 2009, 33 (10) :2166-2173

[10] In search of enantioselective catalysts for the Henry reaction: are two metal centres better than one? [J].

Constable, Edwin C. ;

Zhang, Guoqi ;

Housecroft, Catherine E. ;

Neuburger, Markus ;

Schaffner, Silvia ;

Woggon, Wolf-D. .

NEW JOURNAL OF CHEMISTRY, 2009, 33 (05) :1064-1069

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