1,4-Naphthalenedicarboxylic acid functionalized phosphomolybdate: Synthesis, crystal structure and optical properties

被引：9

作者：

Huang-Fu, You-Jing ^{[1
]}

Chen, Xue-Yan ^{[1
]}

Yang, Wei ^{[1
]}

Bai, Yan ^{[1
,2
]}

Dang, Dong-Bin ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Key Lab Polyoxometalate Chem Henan Prov, Kaifeng 475004, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

MATERIALS LETTERS | 2015年 / 155卷

关键词：

Polyoxometalate; Carboxylic acid; Crystal structure; Luminescence; LUMINESCENT PROPERTIES; POLYOXOMETALATE; LIGAND; CLUSTER; CONSTRUCTION; POLYMERS;

D O I：

10.1016/j.matlet.2015.04.102

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

One inorganic-organic hybrid phosphomolybdate H-12[(PMo6O21)(2)(1,4-NDC)(3)]center dot 37.5H(2)O (1) (1,4H(2)NDC=1,4-naphthalenedicarboxylic acid) has been synthesized and well-characterized. Compound 1 exhibits a lantern-type dimer constructed by Mo-O-C bonds between a couple of [PM06021](3-) polyoxoanions and three 1,4-NDC2- ligands, and displays obvious fluorescent emission at room temperature as a result of the use of functional organic component. The spectroscopic experiments show that compound 1 displays a sensitive and reversible fluorescence response to the pH values in the aqueous solution. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：48 / 50

页数：3

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