Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution

被引：28

作者：

Chai, Xiaomin ^{[1
]}

Huang, Hai-Hua ^{[2
]}

Liu, Huiping ^{[1
]}

Ke, Zhuofeng ^{[2
]}

Yong, Wen-Wen ^{[3
]}

Zhang, Ming-Tian ^{[3
]}

Cheng, Yuan-Sheng ^{[1
]}

Wei, Xian-Wen ^{[1
]}

Zhang, Liyan ^{[1
]}

Yuan, Guozan ^{[1
]}

机构：

[1] Anhui Univ Technol, Sch Chem & Chem Engn, Maanshan 243032, Peoples R China

[2] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China

[3] Tsinghua Univ, Dept Chem, CBMS, Beijing 100084, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 27期

关键词：

VISIBLE-LIGHT; CARBON-DIOXIDE; REDUCTION; COMPLEX; CATALYSIS; WATER; OXIDATION; PROGRESS;

D O I：

10.1039/d0cc00879f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five molecular complexes with different non-noble metal centers were synthesized. The Co-based complex displays the highest photocatalytic performance for CO2 to CO conversion in aqueous media. It achieves high activity (TON = 41 017 and TOF = 3.80 s(-1)) and selectivity (87%) for the production of CO.

引用

页码：3851 / 3854

页数：4

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