Photolysis of atmospheric ozone in the ultraviolet region

被引：145
作者：
Matsumi, Y [1 ]
Kawasaki, M
机构：
[1] Nagoya Univ, Solar Terr Environm Lab, Toyokawa 4428505, Japan
[2] Nagoya Univ, Grad Sch Sci, Toyokawa 4428505, Japan
[3] Kyoto Univ, Dept Mol Engn, Kyoto 606, Japan
[4] Kyoto Univ, Grad Sch Global Environm Studies, Kyoto 6068501, Japan
来源：
CHEMICAL REVIEWS | 2003年 / 103卷 / 12期
关键词：
D O I：
10.1021/cr0205255
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photodissociation processes in the ultraviolet photolysis of ozone were studied. The formation process of O(1D) atoms from the ozone photolysis was also discussed. The fourier transform spectrometer, spectrophotometer and chemical actinometer were used for the measurement of the absorption spectra and the O(1D) quantum yields in the ozone photolysis. It was observed that the O(1D) formation following ozone photolysis at wavelengths greater than 310 nm was due to absorption by vibrationally excited ozone and photodissociation through the spin-forbidden process.
引用
收藏
页码：4767 / 4781
页数：15
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