Photolysis of atmospheric ozone in the ultraviolet region

被引：145
作者：
Matsumi, Y [1 ]
Kawasaki, M
机构：
[1] Nagoya Univ, Solar Terr Environm Lab, Toyokawa 4428505, Japan
[2] Nagoya Univ, Grad Sch Sci, Toyokawa 4428505, Japan
[3] Kyoto Univ, Dept Mol Engn, Kyoto 606, Japan
[4] Kyoto Univ, Grad Sch Global Environm Studies, Kyoto 6068501, Japan
来源：
CHEMICAL REVIEWS | 2003年 / 103卷 / 12期
关键词：
D O I：
10.1021/cr0205255
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photodissociation processes in the ultraviolet photolysis of ozone were studied. The formation process of O(1D) atoms from the ozone photolysis was also discussed. The fourier transform spectrometer, spectrophotometer and chemical actinometer were used for the measurement of the absorption spectra and the O(1D) quantum yields in the ozone photolysis. It was observed that the O(1D) formation following ozone photolysis at wavelengths greater than 310 nm was due to absorption by vibrationally excited ozone and photodissociation through the spin-forbidden process.
引用
收藏
页码：4767 / 4781
页数：15
相关论文
共 50 条
  • [31] THE FLASH PHOTOLYSIS OF OZONE
    MCGRATH, WD
    NORRISH, RGW
    PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1957, 242 (1230): : 265 - &
  • [32] UV PHOTOLYSIS OF OZONE
    AMIMOTO, ST
    FORCE, AP
    WIESENFELD, JR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 341 - 341
  • [33] Atmospheric ozone trends and other factors of surface ultraviolet radiation variability
    Kondratyev, KY
    Pokrovsky, OM
    Varotsos, CA
    ENVIRONMENTAL CONSERVATION, 1995, 22 (03) : 259 - 261
  • [34] PHOTOLYSIS OF OZONE IN THE ULTRAVIOLET REGION - REACTIONS OF O(1D), O2(1DELTAG) AND O2
    ARNOLD, I
    COMES, FJ
    CHEMICAL PHYSICS, 1980, 47 (01) : 125 - 130
  • [35] Spectroscopy. The spectrum of emission of the ozone in the ultraviolet region.
    Janin, J
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1938, 207 : 145 - 146
  • [36] THE ULTRAVIOLET PHOTOLYSIS OF TETRACHLORODIBENZOFURANS
    MAZER, T
    HILEMAN, FD
    CHEMOSPHERE, 1982, 11 (07) : 651 - 661
  • [37] Ultraviolet photolysis of CIOOCI
    Moore, TA
    Okumura, M
    Seale, JW
    Garton, DJ
    Minton, TK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 196 - PHYS
  • [38] Eco-Friendly Cotton/Linen Fabric Treatment Using Aqueous Ozone and Ultraviolet Photolysis
    Hamada, Kengo
    Ochiai, Tsuyoshi
    Tsuchida, Yasuyuki
    Miyano, Kyohei
    Ishikawa, Yosuke
    Nagura, Toshinari
    Kimura, Noritaka
    CATALYSTS, 2020, 10 (11) : 1 - 12
  • [39] PHOTOLYSIS OF OZONE BY ULTRAVIOLET-RADIATION .6. REACTIONS OF O(1D)
    GIACHARDI, DJ
    WAYNE, RP
    PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1972, 330 (1580) : 131 - +
  • [40] Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region
    Steiner, A. L.
    Tawfik, A. B.
    Shalaby, A.
    Zakey, A. S.
    Abdel-Wahab, M. M.
    Salah, Z.
    Solmon, F.
    Sillman, S.
    Zaveri, R. A.
    CLIMATE RESEARCH, 2014, 59 (03) : 207 - 228
12345