Corrosion Behaviour of Mild Steel in Sulphuric Acid Solution in Presence of Ceftazidime

被引:0
|
作者
Singh, Ashish Kumar [1 ]
Shukla, Sudhish Kumar [1 ]
Quraishi, M. A.
机构
[1] Banaras Hindu Univ, Inst Technol, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源
关键词
Adsorption; corrosion; EIS; ceftazidime; mild steel; ADSORPTION PROPERTIES; INHIBITION; DERIVATIVES; IRON;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The corrosion inhibition properties of ceftadizime (CZD) for mild steel corrosion in H2SO4 solution were analysed by electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and gravimetric methods. Mixed mode of adsorption (Physisorption and chemisorption) is proposed for the inhibition and the process followed the Langmuir adsorption isotherm. The mechanism of adsorption inhibition and type of adsorption isotherm were proposed from the trend of inhibition efficiency with temperature, E-a and Delta G(ads)(o). Potentiodynamic polarization study clearly revealed that CZD acted as mixed type inhibitor. The experimental data showed a frequency distribution and therefore a modelling element with frequency dispersion behaviour and a constant phase element (CPE) have been used.
引用
收藏
页码:5802 / 5814
页数:13
相关论文
共 50 条
  • [21] Synergistic Effect of Nizoral and Iodide Ions on the Corrosion Inhibition of Mild Steel in Sulphuric Acid Solution
    Obot, Ime B.
    PORTUGALIAE ELECTROCHIMICA ACTA, 2009, 27 (05) : 539 - 553
  • [22] THE ELECTROCHEMICAL BEHAVIOUR OF STAINLESS STEEL IN SULPHURIC ACID SOLUTION
    BUNE, NJ
    KOLOTYRKIN, JM
    DOKLADY AKADEMII NAUK SSSR, 1956, 111 (05): : 1050 - 1053
  • [23] Effect of polyacrylic acid on the corrosion behaviour of aluminium in sulphuric acid solution
    Umoren, Saviour A.
    Li, Ying
    Wang, Fuhui H.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (12) : 2293 - 2305
  • [24] Effect of polyacrylic acid on the corrosion behaviour of aluminium in sulphuric acid solution
    Saviour A. Umoren
    Ying Li
    Fuhui H. Wang
    Journal of Solid State Electrochemistry, 2010, 14 : 2293 - 2305
  • [25] Cysteine as Inhibitor on the Corrosion of Mild Steel in Sulphuric Acid and Hydrochloric Acid Solutions
    Cang, Hui
    Shi, Wenyan
    Lu, Yu
    Shao, Jingling
    Xu, Qi
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (08) : 3675 - 3678
  • [26] Corrosion behavior of mild steel in the presence of scale inhibitor in sulfuric acid solution
    Yavuz Sürme
    A. Ali Gürten
    Emel Bayol
    Protection of Metals and Physical Chemistry of Surfaces, 2011, 47 : 117 - 120
  • [27] Corrosion behavior of mild steel in the presence of scale inhibitor in sulfuric acid solution
    Surme, Yavuz
    Gurten, A. Ali
    Bayol, Emel
    PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (01) : 117 - 120
  • [28] A pyrazine derivative as corrosion inhibitor for steel in sulphuric acid solution
    Bouklah, M
    Attayibat, A
    Kertit, S
    Ramdani, A
    Hammouti, B
    APPLIED SURFACE SCIENCE, 2005, 242 (3-4) : 399 - 406
  • [29] Musa Paradisiaca Extract as a Green Inhibitor for Corrosion of Mild Steel in 0.5 M Sulphuric Acid Solution
    Mayanglambam, Ramananda S.
    Sharma, Vivek
    Singh, Gurmeet
    PORTUGALIAE ELECTROCHIMICA ACTA, 2011, 29 (06) : 405 - 417
  • [30] Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: Experimental and theoretical investigation
    Obot, I. B.
    Obi-Egbedi, N. O.
    CORROSION SCIENCE, 2010, 52 (01) : 198 - 204