An investigation of the mode of sorption of inositol hexaphosphate to goethite

被引:63
作者
Johnson, Bruce B. [1 ]
Quill, Eben [1 ]
Angove, Michael J. [1 ]
机构
[1] La Trobe Univ, Colloid & Environm Chem Lab, Bendigo, Vic 3552, Australia
关键词
Adsorption; Inositol hexaphosphate; Phytate; Goethite; ATR-FTIR; Outer-sphere complexation; Hydrogen-bonding; BENZENECARBOXYLATE SURFACE COMPLEXATION; (ALPHA-FEOOH)/WATER INTERFACE; MYOINOSITOL HEXAPHOSPHATE; CLAY-MINERALS; ADSORPTION; PHOSPHORUS; IONS; ACID; SOIL; GLUCOSE-1-PHOSPHATE;
D O I
10.1016/j.jcis.2011.09.066
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Adsorption of inositol hexaphosphate (IP6) on goethite has been studied as a function of pH and concentration, and by use of Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR). While adsorption was highest at low pH, a significant amount remained adsorbed above pH 10 where, in the absence of IP6, the surface is expected to have a net negative charge. The adsorption isotherm at pH 5.5 indicated strong binding to the surface with each adsorbed species occupying about 2.5 nm(2). ATR-FTIR spectra of IP6 solutions in the pH range from 2 to 12 were fitted with a single set of IR bands which were assigned primarily by analogy with phosphate spectra. From its variation in intensity with pH the band at 1040 cm(-1) was assigned to the effect of hydrogen bonding on the P-O vibration. No additional bands were required to fit the spectra of IP6 adsorbed to goethite, indicating that adsorption occurs by outer-sphere complexation in this system. At all pH values studied the band associated with hydrogen bonding was more intense for the adsorbed species than in solution at the corresponding pH indicating that hydrogen bonding plays an important role in binding IP6 to goethite. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码:436 / 442
页数:7
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