BiFeO3-synthesis, characterization and its photocatalytic activity towards doxorubicin degradation from water

被引：38
作者：
Dumitru, Raluca [1 ]
Ianculescu, Adelina [2 ]
Pacurariu, Cornelia [1 ]
Lupa, Lavinia [1 ]
Pop, Aniela [1 ]
Vasile, Bogdan [2 ]
Surdu, Adrian [2 ]
Manea, Florica [1 ]
机构：
[1] Politehn Univ Timisoara, Fac Ind Chem & Environm Engn, Piata Victoriei 2, RO-300006 Timisoara, Romania
[2] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Dept Oxide Mat Sci & Engn, Gh Polizu St 1-7, Bucharest 0011061, Romania
来源：
CERAMICS INTERNATIONAL | 2019年 / 45卷 / 02期
关键词：
Bismuth ferrite; Oxalate precursor; Photocatalytic activity; Doxorubicin; BIFEO3; NANOPARTICLES; HYDROTHERMAL SYNTHESIS; ELECTRICAL-PROPERTIES; PHASE-TRANSITIONS; RHODAMINE-B; FERRITE; SIZE; 1,2-ETHANEDIOL; NANOPOWDER; PEROVSKITE;
D O I：
10.1016/j.ceramint.2018.07.298
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Pure bismuth ferrite was successfully obtained through the thermolysis of new bismuth ferrioxalate coordination compound, namely BiFe(C2O4)(3)center dot 3H(2)O. The synthesized precursor was characterized by chemical analysis, infrared spectroscopy and thermal analysis. The bismuth ferrite obtained after a heating treatment of the precursor for at 450-800 degrees C/1 h was investigated by X-ray diffraction, FE-SEM, TEM and HRTEM. The obtained pure bismuth ferrite nanoparticles (480 degrees C) was tested as photocatalyst towards the degradation of doxorubicin (DOX), a well-known anti-cancer drug commonly used for the treatment of various cancer types, which has been detected in hospital effluent water. The comparative results of DOX degradation through photolysis and photocatalysis under UV irradiation showed a great photocatalytic activity of bismuth ferrite towards DOX degradation and mineralization from water. The kinetics aspects were discussed based on the first-order kinetics model that fitted the best the experimental photocatalysis results.
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收藏
页码：2789 / 2802
页数：14
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