Reaction of ethylene with oxygen adsorbed on a silver film. Dependence of the selectivity to ethylene oxide on the ethylene pressure

被引：2

作者：

Khasin, AV ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1998年 / 64卷 / 02期

关键词：

ethylene; catalytic oxidation; silver; reaction kinetics;

D O I：

10.1007/BF02475347

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetics of the reaction of ethylene with oxygen adsorbed on a silver film was studied by a static method at 333 K, initial surface coverage with oxygen close to 0.8 and initial ethylene pressures of 1.1 and 4.4 Pa. The ethylene oxide selectivity was found to increase with increasing ethylene pressure.

引用

页码：289 / 294

页数：6

共 10 条

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[4] GONCHAROVA SN, 1991, KINET KATAL, V32, P854
[5] GRUVER VS, 1974, THESIS I CATALYSIS N
[6] KHASIN AV, 1993, KINET CATAL+, V34, P42
[7] Interaction of oxygen adsorbed on silver film with hydrogen and ethylene
Khasin, AV
Nechaev, SV
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1996, 58 (01): : 125 - 132
[8] KHASIN AV, 1985, KINET KATAL, V26, P1159
[9] SACHTLER WMH, 1981, CATAL REV, V23, P127, DOI 10.1080/03602458108068072
[10] TEMKIN MI, 1985, PROBL KINET KATAL, V19, P73

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