Chemoenzymatic synthesis of branched polymers

被引：35
|
作者：
Peeters, JW
Palmans, ARA
Meijer, EW
Koning, CE
Heise, A
机构：
[1] Tech Univ Eindhoven, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
[2] Tech Univ Eindhoven, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 09期
关键词：
atom transfer radical polymerization (ATRP); branched; chemoenzymatic; enzymes;
D O I：
10.1002/marc.200500011
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl alpha-bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).
引用
收藏
页码：684 / 689
页数：6
相关论文
共 50 条
  • [21] Synthesis of branched polymers by cationic polymerization
    Charleux, Bernadette
    Faust, Rudolf
    Advances in Polymer Science, 1999, 142 : 2 - 69
  • [22] A General Strategy for the Chemoenzymatic Synthesis of Asymmetrically Branched N-Glycans
    Wang, Zhen
    Chinoy, Zoeisha S.
    Ambre, Shailesh G.
    Peng, Wenjie
    McBride, Ryan
    de Vries, Robert P.
    Glushka, John
    Paulson, James C.
    Boons, Geert-Jan
    SCIENCE, 2013, 341 (6144) : 379 - 383
  • [23] Chemoenzymatic synthesis of glycoconjugate polymers starting from nonreducing disaccharides
    Miura, Y
    Wada, N
    Nishida, Y
    Mori, H
    Kobayashi, K
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (18) : 4598 - 4606
  • [24] CHEMOENZYMATIC SYNTHESIS OF OPTICALLY-ACTIVE (METH)ACRYLIC POLYMERS
    MARGOLIN, AL
    FITZPATRICK, PA
    DUBIN, PL
    KLIBANOV, AM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) : 4693 - 4694
  • [25] Highly efficient chemoenzymatic synthesis of novel branched thiooligosaccharides by substrate direction with glucansucrases
    Hellmuth, Hendrik
    Hillringhaus, Lars
    Hoebbel, Sven
    Kralj, Slavko
    Dijkhuizen, Lubbert
    Seibel, Juergen
    CHEMBIOCHEM, 2007, 8 (03) : 273 - 276
  • [26] Chemoenzymatic Synthesis of Branched Glycopolymer Brushes as the Artificial Glycocalyx for Lectin Specific Binding
    Wang, Yuzhen
    Gu, Lei
    Xu, Fanli
    Xin, Fengxue
    Ma, Jiangfeng
    Jiang, Min
    Fang, Yan
    LANGMUIR, 2019, 35 (13) : 4445 - 4452
  • [27] Chemoenzymatic synthesis of glyco-conjugate polymers: Greening synthesis of biomaterials.
    Miura, Y
    Sato, H
    Ikeda, T
    Wada, N
    Kobayashi, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U500 - U500
  • [28] Synthesis of Branched Polymers and Their Application as Functional Materials
    Nabae, Yuta
    Kakimoto, Masaaki
    SEN-I GAKKAISHI, 2016, 72 (07) : 328 - 329
  • [29] Synthesis of branched polymers and their application as functional materials
    Nabae, Yuta
    Kakimoto, Masaaki
    Journal of Fiber Science and Technology, 2016, 72 (07): : 328 - 329
  • [30] Chemoenzymatic synthesis of sulfur-linked sugar polymers as heparanase inhibitors
    He, Peng
    Zhang, Xing
    Xia, Ke
    Green, Dixy E.
    Baytas, Sultan
    Xu, Yongmei
    Pham, Truong
    Liu, Jian
    Zhang, Fuming
    Almond, Andrew
    Linhardt, Robert J.
    DeAngelis, Paul L.
    NATURE COMMUNICATIONS, 2022, 13 (01)
12345