Chemoenzymatic synthesis of branched polymers

被引：35
|
作者：
Peeters, JW
Palmans, ARA
Meijer, EW
Koning, CE
Heise, A
机构：
[1] Tech Univ Eindhoven, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
[2] Tech Univ Eindhoven, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 09期
关键词：
atom transfer radical polymerization (ATRP); branched; chemoenzymatic; enzymes;
D O I：
10.1002/marc.200500011
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl alpha-bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).
引用
收藏
页码：684 / 689
页数：6
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