Facile synthesis of magnetic homochiral metal-organic frameworks for "enantioselective fishing''

被引：58

作者：

Chang, Cui-Lan ^{[1
]}

Qi, Xiao-Yue ^{[1
]}

Zhang, Jiang-Wei ^{[2
]}

Qiu, Ya-Ming ^{[3
]}

Li, Xian-Jiang ^{[1
]}

Wang, Xin ^{[1
]}

Bai, Yu ^{[1
]}

Sun, Jun-Liang ^{[3
]}

Liu, Hu-Wei ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Inst Analyt Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 17期

基金：

中国国家自然科学基金;

关键词：

CHROMATOGRAPHIC RESOLUTION; ASYMMETRIC CATALYSIS; HYDROGEN STORAGE; SEPARATION; ADSORPTION; SULFOXIDES; ENANTIOSEPARATION; RECOGNITION; CHEMISTRY; CHIRALITY;

D O I：

10.1039/c4cc09988e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnetic functionalized homochiral metal-organic frameworks (MOFs) were prepared and applied to efficient enantioselective fishing of chiral drug intermediates. Under optimized conditions, the enantiomeric excess (ee) value as high as 85.2% was achieved for methyl phenyl sulfoxide (MPS) within 3 min.

引用

页码：3566 / 3569

页数：4

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