Facile synthesis of magnetic homochiral metal-organic frameworks for "enantioselective fishing''

被引：57
|
作者：
Chang, Cui-Lan [1 ]
Qi, Xiao-Yue [1 ]
Zhang, Jiang-Wei [2 ]
Qiu, Ya-Ming [3 ]
Li, Xian-Jiang [1 ]
Wang, Xin [1 ]
Bai, Yu [1 ]
Sun, Jun-Liang [3 ]
Liu, Hu-Wei [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Inst Analyt Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 17期
基金：
中国国家自然科学基金;
关键词：
CHROMATOGRAPHIC RESOLUTION; ASYMMETRIC CATALYSIS; HYDROGEN STORAGE; SEPARATION; ADSORPTION; SULFOXIDES; ENANTIOSEPARATION; RECOGNITION; CHEMISTRY; CHIRALITY;
D O I：
10.1039/c4cc09988e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Magnetic functionalized homochiral metal-organic frameworks (MOFs) were prepared and applied to efficient enantioselective fishing of chiral drug intermediates. Under optimized conditions, the enantiomeric excess (ee) value as high as 85.2% was achieved for methyl phenyl sulfoxide (MPS) within 3 min.
引用
收藏
页码：3566 / 3569
页数：4
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