Recent Development of Samarium Diiodide and Other Samarium Reagents in Organic Transformation

被引：4
|
作者：
Liu, Chen [1 ]
Qi, Yan [1 ]
Liu, Yongjun [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Minist Educ, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Lift Sci, Qingdao 266042, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 41卷 / 06期
关键词：
organic synthesis; coupling reactions; reductions; samarium diiodide; samarium reagents; organosamarium; CARBONYL-COMPOUNDS; DIASTEREOSELECTIVE SYNTHESIS; FORMAL SYNTHESIS; REDUCING POWER; SMI2; ALDEHYDES; KETONES; CONSTRUCTION; CYCLIZATIONS; CHLORIDE;
D O I：
10.6023/cjoc202011034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Since the samarium diiodide was discovered, it has been occupying a key field in organic synthesis due to the excellent ability of both single electron transfer and reduction. Other samarium reagents have also been wildly developed in recent years, such as Sm, allylSmBr, SmI3 and so on. In this review, the reactions mediated by samarium reagents especially SmI2 in latest five years are summarized. It mainly includes three parts: studies on the SmI2 promoted coupling reactions, studies on the coupling reactions promoted by other samarium reagents (Sm, allylSmBr, SmI3, Sm(OTf) 3 etc.), and studies on the samarium reagents promoted organic reduction reactions.
引用
收藏
页码：2202 / 2216
页数：15
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