Continuous Rhodium-Catalyzed Hydroformylation of 1-Octene with Polyhedral Oligomeric Silsesquioxanes (POSS) Enlarged Triphenylphosphine

被引：69
作者：
Janssen, Michele [1 ]
Wilting, Jos [2 ]
Muller, Christian [1 ]
Vogt, Dieter [1 ]
机构：
[1] Eindhoven Univ Technol, Dept Homogeneous Catalysis, NL-5600 MB Eindhoven, Netherlands
[2] Hybrid Catalysis BV, NL-5600 MB Eindhoven, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 42期
关键词：
catalyst recycling; homogeneous catalysis; hydroformylation; rhodium; silsesquioxanes; DENDRIMERS; PHOSPHINE; SELECTIVITY; SEPARATION; ALKENES;
D O I：
10.1002/anie.201001926
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Go with the flow: Homogeneous catalyst recycling can be applied to the production of aldehydes in a continuous flow nanofiltration reactor (see picture) that can operate for an unprecedented period of up to two weeks without showing typical deactivation or leaching phenomena. The catalyst is based on a bulky, rigid, and robust silsesquioxane-modified PPh3 ligand, and combines efficient recovery with high activity and selectivity. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7738 / 7741
页数：4
相关论文
共 27 条
  • [1] β-Cyclodextrins modified by alkyl and poly(ethylene oxide) chains: A novel class of mass transfer additives for aqueous organometallic catalysis
    Badi, Nezha
    Guegan, Philippe
    Legrand, Francois-Xavier
    Leclercq, Loic
    Tilloy, Sebastien
    Monflier, Eric
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 318 (1-2) : 8 - 14
  • [2] Baker R.W., 2000, Membrane Technology and Applications
  • [3] Benaglia M., 2009, RECOVERABLE RECYCLAB
  • [4] Triphenylphosphane-functionalised amphiphilic copolymers:: Tailor-made support materials for the efficient and selective aqueous two-phase hydroformylation of 1-octene
    Bortenschlager, Martin
    Schoellhorn, Nicole
    Wittmann, Anton
    Weberskirch, Ralf
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) : 520 - 528
  • [5] BRYANT DR, 2006, DORDRECHT, V30, P9
  • [6] Cole-Hamilton D.J., 2006, CATALYSIS METAL COMP, V30
  • [7] Homogeneous catalysis - new approaches to catalyst separation, recovery, and recycling
    Cole-Hamilton, DJ
    [J]. SCIENCE, 2003, 299 (5613) : 1702 - 1706
  • [8] Cornils B, 2005, MULTIPHASE HOMOGENEOUS CATALYSIS, VOLS 1 AND 2, P1, DOI 10.1002/9783527619597
  • [9] Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation
    Foster, DF
    Gudmunsen, D
    Adams, DJ
    Stuart, AM
    Hope, EG
    Cole-Hamilton, DJ
    Schwarz, GP
    Pogorzelec, P
    [J]. TETRAHEDRON, 2002, 58 (20) : 3901 - 3910
  • [10] solventless continuous flow homogeneous hydroformylation of 1-octene
    EaStCHEM, School of Chemistry, University of St. Andrews, St. Andrews Fife KY16 9ST, United Kingdom
    [J]. Dalton Trans., 2007, 47 (5531-5538):
123