Mg(0)-promoted debromometalation of gem-difluoropropargyl bromides

被引：22

作者：

Mae, M

Hong, JYA

Hammond, GB ^{[1
]}

Uneyama, K

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

[2] Okayama Univ, Dept Appl Chem, Fac Engn, Okayama 7008530, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 11期

基金：

美国国家科学基金会;

关键词：

magnesium; gem-difluoromethylene; propargylsilane; propargylstannane;

D O I：

10.1016/j.tetlet.2005.01.130

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mg(0)/Me3SiCl was found to be effective for the preparation of difluoropropargylsilanes. This method, using Me3SnCl, produced the corresponding propargylstannane. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1787 / 1789

页数：3

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