Asymmetric Hydroformylation

被引：42

作者：

Claver, Carmen ^{[1
]}

Dieguez, Montserrat ^{[1
]}

Pamies, Oscar ^{[1
]}

Castillon, Sergio ^{[2
]}

机构：

[1] Univ Rovira & Virgili, Dept Phys Chem & Inorgan Chem, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Dept Analyt Chem & Organ Chem, Tarragona 43007, Spain

来源：

CATALYTIC CARBONYLATION REACTIONS | 2006年 / 18卷

关键词：

Aldehydes; Catalysis; Enantioselectivity; Hydroformylation; Intermediates; Rhodium;

D O I：

10.1007/3418_016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This chapter presents the latest achievements reported in the asymmetric hydroformylation of olefins. It focuses on rhodium systems containing diphosphites and phosphine-phosphite ligands, because of their significance in the subject. Particular attention is paid to the mechanistic aspects and the characterization of intermediates in the hydroformylation of vinyl arenes because these are the most important breakthroughs in the area. The chapter also presents the application of this catalytic reaction to vinyl acetate, dihydrofurans and unsaturated nitriles because of its industrial relevance.

引用

页码：35 / 64

页数：30

共 84 条

[1] ASYMMETRIC HYDROFORMYLATION [J].

AGBOSSOU, F ;

CARPENTIER, JF ;

MORTREAUX, A .

CHEMICAL REVIEWS, 1995, 95 (07) :2485-2506

[2] Rhodium-catalysed asymmetric hydroformylation of vinylarenes with chiral P,N-ligands based on DIOP skeleton [J].

Aghmiz, A ;

Masdeu-Bultó, AM ;

Claver, C ;

Sinou, D .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) :111-119

[3]

[Anonymous], CATAL COMMUN

[4]

Arena CG, 2002, EUR J INORG CHEM, P711

[5]

BABIN JE, 1993, Patent No. 9303939

[6] PROGRESS IN HYDROFORMYLATION AND CARBONYLATION [J].

BELLER, M ;

CORNILS, B ;

FROHNING, CD ;

KOHLPAINTNER, CW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) :17-85

[7]

BERGOUNHOU C, 1995, B SOC CHIM FR, V132, P815

[8]

BOTTEGHI C, 1998, TRANSITION METALS OR, V1, P25

[9]

Breeden S, 2000, ANGEW CHEM INT EDIT, V39, P4106, DOI 10.1002/1521-3773(20001117)39:22<4106::AID-ANIE4106>3.0.CO

[10]

2-L

← 1 2 3 4 5 6 7 8 9 →