Sulfuric acid on silica-gel: An inexpensive catalyst for aromatic nitration

被引：181

作者：

Riego, JM

Sedin, Z

Zaldivar, JM

Marziano, NC

Tortato, C

机构：

[1] COMMISS EUROPEAN COMMUNITIES,JOINT RES CTR,SAFETY TECHNOL INST,PROC ENGN DIV,I-21020 ISPRA,ITALY

[2] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 04期

关键词：

D O I：

10.1016/0040-4039(95)02174-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solid acidic catalysts made of sulfuric acid supported on silica-gel and their application to the nitration of aromatics with nitric acid and isopropyl nitrate are described. Substrates with very different levels of activation were investigated. Methods to overcome the poisoning produced by water and to tune the catalyst activity according to the reactivity of the substrate are outlined.

引用

页码：513 / 516

页数：4

共 23 条

[1]

CORNELIS A, 1990, JANSSEN CHIM ACTA, V8, P3

[2] REACTIONS ON SILICA-GEL - BECKMANN REARRANGEMENT OF OXIME PARA-TOLUENESULFONATES [J].