Analysis of fluorescence spectra of oxyfluoride compositions doped with samarium oxide (Sm2O3) and samarium fluoride (SmF3)

被引：0

作者：

Pashova, T. ^{[1
]}

Kostova, I. ^{[2
,3
]}

Eftimov, T. ^{[1
]}

Tonchev, D. ^{[2
,3
]}

机构：

[1] Paisii Hilendarski Univ Plovdiv, Fac Phys, 24 Tsar Asen Str, BG-4000 Plovdiv, Bulgaria

[2] Paisii Hilendarski Univ Plovdiv, Fac Chem, BG-4000 Plovdiv, Bulgaria

[3] Univ Saskatchewan, Lab Elect & Opt Mat, Saskatoon, SK, Canada

来源：

BULGARIAN CHEMICAL COMMUNICATIONS | 2015年 / 47卷

关键词：

samarium; fluorescence; emission spectra; optical materials; GLASSES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ZnO-ZnF2-P2O5-B2O3 compositions, doped with a varying quantity of samarium oxide (Sm2O3) and samarium fluoride (SmF3) have been synthesized. The thermal properties of the obtained compositions have been measured using DSC analysis. Fluorescence spectra measured at different excitation wavelengths are shown. The fluorescence excitation efficiency for varying quantity of Samarium in the samples and the pumping wavelength has been studied. With optical pumping in the 370-490 nm range fluorescence spectra indicating the presence of Sm3+ have been obtained. The widening of the pumping range to higher wavelengths a new fluorescence peak was observed. The range in which the peak is observed was established from the performed analysis and the excitation wavelength of maximum efficiency was determined.

引用

页码：9 / 14

页数：6

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