Synthesis of Poly Alpha Olefins Using Alpha Olefins Obtained from the Steam Cracking Process of Coal Liquefaction Wax

被引:5
作者
Yu, X. [1 ,2 ]
Shen, B. [1 ]
Sun, H. [1 ]
Yang, L. [1 ]
Liu, L. [1 ]
Liu, J. [1 ]
机构
[1] E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
[2] Sinopec Lubricant Co, Beijing, Peoples R China
关键词
coal wax; alpha olefins; lubricant base stocks; oligomerization; poly alpha olefins; LUBRICANTS; CATALYST;
D O I
10.1080/15567036.2012.678960
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Alpha olefins were prepared from the steam cracking process of coal liquefaction wax and the cracking alpha-olefins products were used for the synthesis of poly alpha olefins. Under optimal cracking conditions, the result shows that the yields of liquid and gas are 43.1 and 19.5%, respectively. The single-pass conversion is 62.6% and the a-olefin single-pass yield is 28.4%. Furthermore, the total content of alpha olefins in cracking liquid product reaches 65.9%. The oligomer formed from the cracking product shows lower yield, higher freezing point, higher kinematic viscosity, and lower viscosity index as compared to the oligomer prepared from 1-decene monomer. The oligomers from the cracking product and 1-decene have similar distillation ranges.
引用
收藏
页码:1195 / 1201
页数:7
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