Synthesis and structure of a new open-framework zinc phosphate:: [Zn3(PO4)2(HPO4)0.5]-0.5[(NH3(CH2)2(NH3)]2+H2O

被引：38

作者：

Chidambaram, D ^{[1
]}

Natarajan, S ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Bangalore 560064, Karnataka, India

来源：

MATERIALS RESEARCH BULLETIN | 1998年 / 33卷 / 08期

关键词：

inorganic compounds; microporous materials; chemical synthesis; X-ray diffraction; crystal structure;

D O I：

10.1016/S0025-5408(98)00100-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new open-framework zinc phosphate, [Zn-3(PO4)(2)(HPO4)(0.5)] (-)[0.5(NH3 (CH2)(2)(NH3)]2+H2O, having Zn-O-Zn linkages was synthesized by hydrothermal technique. The structure consists of a network of ZnO4 and PO4 tetrahedra in which the vertices are shared. Water molecules are present in a 6-membered channel and the protonated ethylenediamine molecule is in the middle of a 8-membered channel, creating alternating hydrophobic and hydrophilic channels. (C) 1998 Elsevier Science Ltd.

引用

页码：1275 / 1281

页数：7

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