Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs

被引：19

作者：

Fernandez, Carlos A. ^{[1
]}

Thallapally, Praveen K. ^{[1
]}

Liu, Jun ^{[2
]}

Peden, Charles H. F. ^{[2
]}

机构：

[1] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA

[2] Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 09期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION-FRAMEWORK; SHAPE-SELECTIVITY; H-2; ADSORPTION; DESIGN; FUNCTIONALITY; HYDROGEN; STORAGE; CO2;

D O I：

10.1021/cg100796e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports the influence of alkylation reaction byproducts, particularly HCl, on MOF-5. Reaction between tert-butyl chloride and toluene or biphenyl in the presence of MOF-5 as a catalyst generates an unusual structural transformation which was proved to be due to the formation of byproduct HCl by means of powder X-ray diffraction analysis. Despite this, the highly desirable catalytic performance in terms of high conversions ( > 99%) and selectivity ( > 98%) toward the less bulky para-oriented products is maintained.

引用

页码：4118 / 4122

页数：5

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