On the cleavage process of the N-trifluoromethylsulfonyloxy-1,8-naphthalimide photoacid generator

被引：36
作者：
Malval, Jean-Pierre
Morlet-Savary, Fabrice
Allonas, Xavier
Fouassier, Jean-Pierre
Suzuki, Shota
Takahara, Shigeru
Yamaoka, Tsuguo
机构：
[1] Univ Haute Alsace, CNRS, UMR 7525, Dept Photochem, F-68093 Mulhouse, France
[2] Chiba Univ, Fac Engn, Dept Informat & Image Sci, Chiba 2638522, Japan
来源：
CHEMICAL PHYSICS LETTERS | 2007年 / 443卷 / 4-6期
关键词：
D O I：
10.1016/j.cplett.2007.06.082
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photocleavage mechanism of N-tritluoromethylsulfonyloxy-1,8-naphthalimide usable as a photoacid generator is reported. Stationary fluorescence measurements, picosecond transient spectroscopy, infrared analysis and DFT calculations support a homolytic N-O bond cleavage followed by an internal cyclic rearrangement of the 1,8 naphthalimide core which lead to benz[cd]indol-2(1H)-one, carbon dioxide and sulfonic acid. (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：323 / 327
页数：5
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