Diastereoselective self-assembly of bisheptahelicene on Cu(111)

被引：16

作者：

Mairena, Anais ^{[1
]}

Parschau, Manfred ^{[1
]}

Seibel, Johannes ^{[1
]}

Wienke, Martin ^{[2
]}

Rentsch, Daniel ^{[1
]}

Terfort, Andreas ^{[3
]}

Ernst, Karl-Heinz ^{[1
,4
]}

机构：

[1] Swiss Fed Labs Mat Sci & Technol, Empa, CH-8600 Dubendorf, Switzerland

[2] Univ Hamburg, Inst Organ Chem, D-20146 Hamburg, Germany

[3] Goethe Univ Frankfurt, Inst Anorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany

[4] Univ Zurich, Dept Chem, CH-8057 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 63期

关键词：

RACEMATE CRYSTALS; METAL-SURFACES; CRYSTALLIZATION; HEPTAHELICENE; NUCLEATION;

D O I：

10.1039/c8cc04160a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stereochemical effects during two-dimensional crystallization of bisheptahelicene diastereomers on a Cu(111) surface have been studied with scanning tunnelling microscopy. The (M,M)- and (P,P)-enantiomers crystallize into a monolayer racemate lattice, whereas the (M,P)-diastereomers aggregate into their own monolayer phase.

引用

页码：8757 / 8760

页数：4

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