Diastereoselective self-assembly of bisheptahelicene on Cu(111)

被引:16
|
作者
Mairena, Anais [1 ]
Parschau, Manfred [1 ]
Seibel, Johannes [1 ]
Wienke, Martin [2 ]
Rentsch, Daniel [1 ]
Terfort, Andreas [3 ]
Ernst, Karl-Heinz [1 ,4 ]
机构
[1] Swiss Fed Labs Mat Sci & Technol, Empa, CH-8600 Dubendorf, Switzerland
[2] Univ Hamburg, Inst Organ Chem, D-20146 Hamburg, Germany
[3] Goethe Univ Frankfurt, Inst Anorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany
[4] Univ Zurich, Dept Chem, CH-8057 Zurich, Switzerland
关键词
RACEMATE CRYSTALS; METAL-SURFACES; CRYSTALLIZATION; HEPTAHELICENE; NUCLEATION;
D O I
10.1039/c8cc04160a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Stereochemical effects during two-dimensional crystallization of bisheptahelicene diastereomers on a Cu(111) surface have been studied with scanning tunnelling microscopy. The (M,M)- and (P,P)-enantiomers crystallize into a monolayer racemate lattice, whereas the (M,P)-diastereomers aggregate into their own monolayer phase.
引用
收藏
页码:8757 / 8760
页数:4
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