Synthesis and characteristics of a novel, high-nitrogen, heat-resistant, insensitive material (NOG2Tz)

被引:26
作者
Fu, Zhanda [1 ]
He, Cheng [1 ]
Chen, Fu-xue [1 ]
机构
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
关键词
CARBON NITRIDES; DERIVATIVES; TETRAZINES;
D O I
10.1039/c1jm14232a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The novel, high-nitrogen, energetic compound, 3,6-bis(3-nitro-1,2,4-oxadiazole-5-guanyl)-1,2,4,5-tetrazine (NOG(2)Tz, 8, N 53.08%), was synthesised and fully characterised. Thermal decomposition kinetics and several thermodynamic parameters were obtained under non-isothermal conditions by DSC. NOG(2)Tz exhibits a high density and was calculated to have favourable detonation properties. It is thermally stable (T-dec. 328 degrees C) and remarkably insensitive to impact.
引用
收藏
页码:60 / 63
页数:4
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