A facile synthesis of quinoxalines by using SO42-/ZrO2-TiO2 as an efficient and recyclable heterogeneous catalyst

被引：11

作者：

Shelke, Sushil, V ^{[1
]}

Dhumal, Sambhaji T. ^{[2
]}

Karale, Akshay Y. ^{[1
]}

Deshmukh, Tejshri R. ^{[3
]}

Patil, Meghshyam K. ^{[1
]}

机构：

[1] Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem, Sub Campus, Osmanabad 413501, India

[2] Ramkrishna Paramhansa Mahavidyalaya, Dept Chem, Osmanabad, India

[3] Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem, Aurangabad, Maharashtra, India

来源：

SYNTHETIC COMMUNICATIONS | 2022年 / 52卷 / 04期

关键词：

SO42-; ZrO2-TiO2; quinoxalines; recyclable; heterogeneous catalyst; cyclocondensation; ACID CATALYST; PHOTOCATALYTIC DEGRADATION; SULFATED ZIRCONIA; GREEN SYNTHESIS; SOLVENT-FREE; DERIVATIVES; WATER; 1,2-DIAMINES; CYCLIZATION; CONVENIENT;

D O I：

10.1080/00397911.2022.2039711

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Quinoxaline derivatives have been synthesized in good to excellent yields by the cyclocondensation reaction of o-pheneylenediamine with substituted phenacyl bromides/benzil in the presence of SO42-/ZrO2-TiO2 as an efficient and heterogeneous catalyst. The catalyst can be recovered up to five catalytic cycles without significant loss in catalytic activity. The reported SO42-/ZrO2-TiO2 catalyst has been thoroughly characterized by using infrared spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X-ray diffraction (XRD). Here, we have used ethanol as a green solvent in this cyclocondensation. This new method has several advantages, such as excellent yields, short reaction time, nontoxic, and easily recoverable catalyst.

引用

页码：597 / 607

页数：11

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