Synthesis, X-ray characterization and regium bonding interactions of a trichlorido(1-hexylcytosine)gold(iii) complex

被引：31

作者：

Terron, Angel ^{[1
]}

Buils, Jordi ^{[1
]}

Mooibroek, Tiddo J. ^{[2
]}

Barcelo-Oliver, Miquel ^{[1
]}

Garcia-Raso, Angel ^{[1
]}

Fiol, Juan J. ^{[1
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Chem, Crts Valldemossa Km 7-6, Palma De Mallorca 07122, Baleares, Spain

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 24期

关键词：

GOLD(III); GOLD; COORDINATION; CHEMISTRY; BINDING; MODEL; NUCLEOBASES; FUTURE; RADII; VAN;

D O I：

10.1039/d0cc00505c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we report the synthesis and X-ray characterization of a gold(iii) complex of 1-hexylcytosine via N(3). The AuCl3N complexes stack on top of each other by reciprocal [AuMIDLINE HORIZONTAL ELLIPSISCl] regium bonding interactions. After the first example 35 years ago, this is the second available structure of a cytosine nucleobase model complexed to gold(iii).

引用

页码：3524 / 3527

页数：4

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