Diapua(2,2′-diamino-4,4′-bi-1,3-thiazole)oxosulfatovanadium(IV) tetrahydrate

被引：6
|
作者：
Wu, ZY [1 ]
Li, YT
Xu, DJ
机构：
[1] Ocean Univ China, Marine Drug & Food Inst, Qingdao 266003, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270105028982
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [VO(SO4)(C6H6N 4S2)(H2O)2]·4H2O, displays a distorted octahedral coordination geometry. The 2,2′-diamino-4, 4′-bithiazole ligand is present in the usual chelating bidentate mode. The sulfate ligand coordinates in a monodentate fashion to the V atom. A large displacement of the V atom from the equatorial plane towards the oxo group correlates with the strong V=O double bond. In the crystal structure, a three-dimensional supramolecular network is formed by hydrogen bonds. © 2005 International Union of Crystallography.
引用
收藏
页码：M463 / M465
页数：3
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